hemical Reactions of Alcohols:Predict the products formed by hydration of the following alkenes.a) 1-hexeneb) 2-hexenec) 2-methyl-3-hexened) 2,2-dimethyl-3-hepteneWhat product/s wbuld result from the oxidation of each of the following alcohols withxample: potassium permanganate? If no reaction occurs, write NR.a) 2-butanolb) 2-methy-2-hexanolc) Cyclohexanold) 1-methyl-1-cyclopentanol

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hemical Reactions of Alcohols: Predict the products formed by hydration of the following alkenes. a) 1-hexene b) 2-hexene c) 2-methyl-3-hexene d) 2,2-dimethyl-3-heptene What product/s would result from the oxidation of each of the following alcohols with xample: potassium permanganate? If no reaction occurs, write NR. a) 2-butanol b) 2-methyl-2-hexanol c) Cyclohexanol d) 1-methyl-1-cyclopentanol

hemical Reactions of Alcohols: Predict the products formed by hydration of the following alkenes. a) 1-hexene b) 2-hexene c) 2-methyl-3-hexene d) 2,2-dimethyl-3-heptene What product/s would result from the oxidation of each of the following alcohols with xample: potassium permanganate? If no reaction occurs, write NR. a) 2-butanol b) 2-methyl-2-hexanol c) Cyclohexanol d) 1-methyl-1-cyclopentanol

Macroscale and Microscale Organic Experiments

7th Edition

ISBN:9781305577190

Author:Kenneth L. Williamson, Katherine M. Masters

Publisher:Kenneth L. Williamson, Katherine M. Masters

Chapter19: Alkenes From Alcohols: Cyclohexene From Cyclohexanol

Section: Chapter Questions

Problem 3Q

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1. Ethylene glycol, a major component of antifreeze, becomes especially poisonous when it is oxidized by the liver. Draw two oxidation products that could be derived from ethylene glycol. 2.When 2-methyl-1-butanol is dehydrated in an acid medi- um to an alkene, it yelds mainly 2-methyl-2-butene rather than 2-methyl-1-butene. This indicates that the dehydra- tion to an alkene is at least a two-step reaction. Suggest a mechanism to explain the reaction.
Some of the most useful compounds for organic synthesisare Grignard reagents (general formula R-MgX, where X is ahalogen), which are made by combining an alkyl halide, R-X,with Mg. They are used to change the carbon skeleton of a start-ing carbonyl compound in a reaction similar to that with R-Li:.(a) What is the product, after a final step with water, of thereaction between ethanal and the Grignard reagent of bromo-benzene? (b) What is the product, after a final step with water, ofthe reaction between 2-butanone and the Grignard reagent of2-bromopropane? (c) There are often two (or more) combina-tions of Grignard reagent and carbonyl compound that will givethe same product. Choose another pair of reactants to give theproduct in (a). (d) What carbonyl compound must react with aGrignard reagent to yield a product with the -OH group at theendof the carbon chain? (e) What Grignard reagent and carbonylcompound would you use to prepare 2-methyl-2-butanol?
Identify the organic functional group of the product, the reaction type, and predict the functional group of the reactant. Then choose the most likely reactant from the reaction below.The product is a(n)a. aldehydeb. aromaticc. alcohold. alkanee. alkeneThe reaction type is :a. oxidationb. hydrationc. reduction (hydrogenation)d. hydrolysise. dehydrationThe reactant should be a(n)a. ketoneb. alkenec. alkaned. alcohole. esterThe most likely reactant is molecule :a. Bb. Ac. Dd. CFor the answers I got alcohol, hydrolysis, alkene, and C. But I got one of them wrong. What are the correct answers?
Identify the organic functional group of the product, the reaction type, and predict the functional group of the reactant. Then choose the most likely reactant from the reaction below.The product is a(n)a. aldehydeb. aromaticc. alcohold. alkanee. alkeneThe reaction type is :a. oxidationb. hydrationc. reduction (hydrogenation)d. hydrolysise. dehydrationThe reactant should be a(n)a. ketoneb. alkenec. alkaned. alcohole. esterThe most likely reactant is molecule :a. Bb. Ac. Dd. C
Alkenes can be converted to alcohols by reaction with mercuric acetate to form a β-hydroxyalkylmercury(II) acetate compound, a reaction called oxymercuration. Subsequent reduction with NaBH4 reduces the C–Hg bond to a C–H bond, forming the alkyl alcohol, a reaction called demercuration. Draw the structures of the Hg-containing compound(s) and the final alcohol product(s) formed in the following reaction sequence, omitting byproducts. If applicable, draw hydrogen at a chirality center and indicate stereochemistry via wedge-and-dash bonds.
Identify the organic functional group of the product, the reaction type, and predict the functional group of the reactant. Then choose the most likely reactant from the reaction below.The product is a(n)a. aromaticb. alkenec. aldehyded. alcohole. etherThe reaction type is :a. dehydrationb. oxidationc. reduction (hydrogenation)d. hydratione. hydrolysisThe reactant should be a(n)a. aldehydeb. alkenec. esterd. alkynee. alcoholThe most likely reactant is molecule :a. Both C and D would form the productb. D onlyc. Bd. C onlye. A
What products would you expect to obtain from the oxidation of thefollowing alcohols with CrO3? a. Cyclohexanol b. 1-hexanol
Ethers (general formula R—O—R)have many important uses. Until recently,methyl tert-butyl ether (MTBE, right)was used as an octane booster and fueladditive for gasoline. It increases the oxy-gen content of the fuel, which reducesCO emissions. MTBE is synthesized bythe catalyzed reaction of 2-methylpropene with methanol.(a) Write a balanced equation for the synthesis of MTBE. (Hint:Alcohols add to alkenes similarly to the way water does.)(b) If the government required that auto fuel mixtures contain2.7% oxygen by mass to reduce CO emissions, how many gramsof MTBE would have to be added to each 100. g of gasoline?(c) How many liters of MTBE would be in each liter of fuel mix-ture? (The density of both gasoline and MTBE is 0.740 g/mL.)(d) How many liters of air (21% O₂ by volume) are needed at24C and 1.00 atm to fully combust 1.00 L of MTBE?
Draw the organic product(s) formed upon the addition of HBr to (a) 2-methyl-2-pentene, (b) trans-2-hexene, and (c) 4-methylcyclohexene. How many regioisomers can be formed in each case?
what starting materials and reagents could form the indicated product ? Fill in the reaction, acco unt for H indicated as being from the reaction 1.2.3.4.5
Identify the organic functional groups and reaction type for the following reaction if only the major product is shown.The reactant is a(n)a. alkyneb. etherc. alkened. alcohole. aromaticThe product is a(n)a. tertiary alcoholb. primary alcoholc. aldehyded. ethere. secondary alcoholThe reaction type is :a. hydrolysisb. hydrationc. reduction (hydrogenation)d. dehydratione. oxidation
Write a complete chemical equation showing reactants, products, and catalysts needed(if any) for the following reaction and (2) Draw and name the organic compound found inevery reaction.(Use condensed structural formula) (A) Reaction of cis-3,3-Dimethyl-4-propylocta-1,5-diene with two mole of HBr(B) Reaction of trans-1-Bromo-3-chlorocyclopentane with potassium hydroxide(C) Formation of Gilman reagent using isopropyl bromide