Answered: How many electronic spectral bands for…

How many electronic spectral bands for Ni2+ and Co2+ , one could be expected. Assign these electronic d-d transition bands.

Chemistry & Chemical Reactivity

10th Edition

ISBN:9781337399074

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter22: The Chemistry Of The Transistion Elements

Section22.7: Colors Of Coordination Compounds

Problem 2.3ACP: How are the d electrons of Pt distributed in a d-orbital splitting diagram?

See similar textbooks

Related questions

Q: Consider the Tanabe - Sugano diagram for [V(H20)6]²+ octahedral complexes shown below 1. What is the…

A: The most stable electronic arrangement is of lowest energy and is ground state electronic…

Q: According to the selection rules, which ONE of the following coordination complexes will be LESS…

A: The colour is observed in a complex only when the transition take place in visible region Selection…

Q: Predict the d orbital splitting of [Cr(CN)6]4-complex. A) (t2g)3(eg)0 B) (t2g)2(eg)2 C)…

Q: The compound tris-(8-hydroxyquinolato)aluminum(III). Draw the structural isomers for this compound.…

A: Tris(8-hydroxyquinolinato)aluminium is the chemical compound with the formula Al(C9H6NO)3. Point…

Q: Draw all the possible isomers of diamminedihydroxodichlorochromate (III). How many unpaired…

A: The possible isomers of diamminedihydroxodichlorochromate(III) is drawn as follows,

Q: The magnetic moment of compound K3[CoF6] is 5.0 B.M. What is the crystal field stability energy? A.…

Q: The symbol of the spectroscopic term and the number of electronic transitions for the [Ti(H2O)6]2+…

A: The electronic transitions are associated with the excitation of electrons UV and visible range.…

Q: While d-electrons in many transition metal compounds may not be involved directly in bond formation,…

A: While d-electrons in many transition metal compounds may not be involved directly in bond formation,…

Q: Which of the following pairs are coordination isomers? O A. [PtCl4(H2O)2]Cl2 and [PtCl3(H20)2]Cl3 B.…

Q: Which one of the following complexes has a spin of S = 2? A. trans-Ni(H2O)4CI2 B. [Co(CN)6]3- C.…

A: The spin of any coordination compounds depends upon the ligand field strength. A strong field ligand…

Q: [{Co(NH3)5}2(µ-OH)]5+ designation of the complex in the Ewen-Basset system? *K2[OsCl5N] designation…

Q: Use the trans directing effect of ligands to suggest the reaction pathways to synthesize the isomers…

A: the trans effect is the labilization of ligands that are trans to certain other ligands, which can…

Q: Q 1: Iron as for a transition metal and it can adopt different oxidation states.One of the most…

A: Since you have asked multiple question, we will solve the first question for you.If you want any…

Q: Rank the following complexes from smallest to largest d-orbital splitting i) [Fe(CN)6]³- ii)…

Q: Ph. Ph CI Me Pipr2 pipr2 PPH3 Co X.. Ph2 Ph2 PPH3 X = Cl Can someone help me find 1) the formal…

A: Oxidation state: For a metal Oxidation state is defined as degree of oxidation of metal. It is an…

Q: Name the following compounds, using the standard nomenclature rules for coordination complexes. i)…

A: PPh3 is neutral ligand; hence Au is in the +1 oxidation state. Name : [Au(PPh3)3]+ :…

Q: Find out the first row transition metals (M) for the following compounds (all of them obey 18e rule)…

Q: Which one of the following complexes has a spin of S = 2? %3D A. trans-Ni(H2O)4CI2 B. [Co(CN)6]3- C.…

A: Given : Different different complexes. To find : complex that has a spin of S =2. Solution : As we…

Q: Rank the following complexes from smallest to largest d-orbital splitting i) [Fe(CN)6]³- ii)…

A: The d-orbital splitting energy can be calculated by the following relation: Splitting…

Q: What is the electron configuration of the [Fe (CN) 6] 3-complex according to the molecular orbital…

A: In [Fe(CN)6]3-, Let the oxidation number of Fe be x. Then, x+6-1=-3⇒x=+3

Q: Predict the magnetic properties and determine the spin-only moment for the following: [Mn(H2O)6]2+…

Q: Which of the following compounds follow the effective atomic number rule, and which do not?(27Co,…

A: Effective atomic number rule is defined as the total number of electrons present around the central…

Q: 6. Which one of the following would be the highest stretching frequency of carbonyl? (A)…

Q: The cis isomer of tetraamminedichlorocobalt(III) bromide appears red while the trans isomer appears…

Q: Rank the following complexes from smallest to largest d-orbital splitting i) [Fe(CN)6]3- ii)…

A: The complexes given are (i) [Fe(CN)6]3−, (ii) [Fe(CN)6]4−, (iii) [Fe(Cl)6]4−, (iv) [Ru(CN)6]3−

Q: Draw the structures of the stereoisomers possible for [Co(NH3)4Cl2]Cl complex synthesized by Alfred…

Q: What type of isomerism is exhibited by the following pair? NH₂ NO₂ H₂N H₂N O₂N H₂N NH3 O optical O…

A: Fac means Facial i.e. the same ligands form a common face of the polyhedron. Mer means Meridonial…

Q: A complex of formula [M(N = CCH3)6](NO3)2, in which the M(II) ion is that of a firstrow (3d)…

A: Answer: With the help of Magnetic moment, find out the number of unpaired electrons central metal…

Q: Characterize each of t Following CooXDivation comprends M₂₂ [Cr CH₂)₂ (CN)+] [M(NH3)3 Brolls…

Q: 54. In the octahedral complex Co(NH2CH2CO2)3, each glycinate ion NH2CH2CO2¯ binds to cobalt through…

A: This question is related to stereochemistry. Stereoisomers are the molecules having the same…

Q: Draw the structures of all possible isomers for the followingcomplexes. Indicate which isomers are…

A: The structures of all the isomers are given in the following steps.

Q: What type of isomerism is exhibited by the following pair? NH₂ CI H₂N, H₂N NH3 H₂N H₂N NH₂ NH₂…

A: Isomerism means two compounds having dame molecular formula but the different structural formula.

Q: How many electronic spectral bands for Ni^2+ and Co^2+ , one could be expected. Assign these…

A: The common oxidation states of cobalt are +2 and +3. The complexes are either octahedral or…

Q: 5) Rank the following sigma complexes in order of increasing stability. H **$$ Br Br H NO₂ + A H Br…

A: Given:

Q: which of the following species are capable of forming a coordination bond with BF3: a Ca2^+ b NH3…

A: The following species that are capable of forming a coordination bond with BF3 are to be…

Q: SAIC Pr7.1 The compound Na,lrCl, reacts with triphenylphosphine in diethyleneglycol in an atmosphere…

A: Isomers are compounds with same molecular formula but different structural formula.…

Q: spectrum

A: Dear student I have given answer to your question in the image format.

Q: The d-d transition in CrCl4 2- is at lower energy than Cr(NH3)62+. Briefly explain.

A: A question based on d-d transition, which is to be accomplished.

Q: Based on the complex below, what would be the number of Co-Cl vibrational bands that would appear on…

A: According to question, Given complex, trans-CoNH35Cl2+

Q: Calculate the index of hydrogen deficiency of this compound Q.) Aspirin, C9H8O4

Q: Which of the following is a pair of diastereomers? Br Br Br Br CI CI II IV %3D

A: Diastereomers are a type of stereoisomer which are non-mirror, non-identical compound. They are…

Q: Determine the d orbital splitting of [FeCl4]-complex. A) (e)0(t2)5 B) (t2)3(e)2 C) (t2)5(e)0 D)…

Q: a) Explain the d-d transitions for [Ti(H2O)6]3+

Q: Characterize each of the Fallowing COORDINation comprend's M₂ [Cr CH₂)₂ (CN)+] [M(NH3)3 Brg [M₂…

A: Given that, some metal complexes are Mg[Cr(H2O)4(CN)4] [Ni(NH3)3Br5]Cl3 [Mn(H2O)2(C2O4)2] We have…

Q: The physical method which can be used to distinguish between [Mn(acac)3] and acetylacetone is: a. IR…

Q: What is the relationship between the magnitude of ∆ and the energy of the d-d transition for a d1…

Q: What is the spin-only magnetic moment for the [NiCl4]Cl2 complex?

A: Ans- spin-only Magnetic moment of [NiCl4]Cl2 complex is 4.9 BM. Explanation - In the…

Q: 1- The compound with 3 electronic transitions in the UV-Visible spectrum a) [Cr(acaac)] b)…

A: b) [Cu(phthalocyanine)] b) εl.εD and λ a) they have the same absolute configuration

Q: a) Illustrate the transfer of electrons from the ligand to metal ion in hexaaquairon(III) ion,…

A: a) The given complex is hexaaquairon(III) ion, [Fe(H2O)6]+3. The structure of the complex is,

Question

How many electronic spectral bands for Ni2+ and Co2+ , one could be expected. Assign these electronic d-d transition bands.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Step by step

Solved in 4 steps with 4 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Show how to use the microanalysis data to determine the number of cod (C8H12) ligands per Pd. C, 33.65%; H, 4.24%; N, 0.00%; Pd, 37.27%.
Predict the d orbital splitting of [Cr(H2O)6]2+complex. A) (t2g)2(eg)2 B) (t2g)4(eg)0 C) (t2g)3(eg)1 D) (t2g)3(eg)2 E) (t2g)3(eg)0
The electronic configuration of 15 X 3- ion is a. [Ne]3s23p2 b. [Ne]3s2 c. [Ne]3s23p6 d. [Ne]3s23p1
Calculate the index of hydrogen deficiency of this compound Q.) Aspirin, C9H8O4
Determine the LFSE for octahedral ions from first principle and confirm the value matches those in table 2. a)High-spin d5 b)Low-spin d6 c)High-spin d6 d)Low-spin d7 e)High-spin d7
Predict whether the following complexes would show Jahn-Teller distortion: Ammonium pentachlorooxidochromate(V), meff = 1.8 mB Potassium hexaiodidomanganate(IV), meff = 3.8 mB Potassium hexachoridocuprate(II), meff = 1.8 mB Hexaaquamanganese(II) chloride, meff = 6.0 mB
For the following d-electron configurations, find or show the following :a. Electron filling of eg and t2g, for both high and low spin states:b. Calculate the crystal field stabilization energy (CFSE) for both states c. State whether Jahn-Teller effect is expected: indicate elongation/contraction if possible and show the energy levels splitting following Jahn-Teller distortion d4 d5 d7 d8
Given the Tanabe-Sugano diagram below for a d3 complex.Which of the following transitions corresponds to the ∆o?A.4A2g → 4T1g (F)B. 4T2g → 4T1g (P) C.4A2g → 4T1g (P) D.4A2g → 4T2g
Which of the following ligands cannot coordinate in an η1 fashion? Group of answer choices benzene (C6H6) allyl cyclopentadienyl (Cp-) methyl
Elimination of an L ligand (as the first step of a D substitution mechanism) from a charge - neutral NiL4 complex has very little tendency to occur for L = P(OMe3), but for L = PMe3, it occurs almost completely. Since the two ligand species have approximately the same cone angle, what factors are responsible for this difference?
Complexes [Ni(prop)3)^2+ is chiral. Represent the corresponding enantiomers by naming them
What point group is produced if an octahedral (Oh) complex is distorted by stretching two trans M-L bonds and compressing another two trans bonds? D4h D2d D2h C4v