Predict whether the following complexes would show Jahn-Teller distortion: Ammonium pentachlorooxidochromate(V), meff = 1.8 mB Potassium hexaiodidomanganate(IV), meff = 3.8 mB Potassium hexachoridoc

Q: Taking the Jahn Teller effect into account, how many absorptions would you expect from the…

A: The Jahn-Teller effect is a geometric distortion of a non-linear molecular system that reduces its…

Q: Calculate the conditional formation constant (K'' NiY) of the [NiY]2- complex in 0.050 M NH3 and…

A: The chemical reaction corresponding to the mentioned formation constant is:

Q: a) Give electron counts for the following organometallic compounds 16 and 17. Show clearly how you…

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Q: Which option is correct for naming the K3 [Cr (C2O4) 3] .3H2O complex according to the Ewen-Basset…

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Q: Why was conductivity measurement not suitable for determining the structure of the complex…

A: The answer is given as follows

Q: Rank the following ions in the weak octahedral field in order of increasing Jahn-Teller effect.…

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Q: The observed absorption band of the M2+ ion in the electronic spectrum of the hexaaqua complex is…

A: The octahedral complex  is the hexaaqua complex of M2+ ion and ΔE1 is the crystal field splitting…

Q: Co and Ni can be analysed simultaneously by their reaction with 2, 3-quinoxalinedithiol. Molar…

A: According to the question we have  The molar absorptivity of Cobalt complex in 510 nm =ε510Co =36400…

Q: 84 The elements in between Se-Zn 1. ali show paramagnetism 2 form ocloured hydrated ions in aquecus…

A: Answer 84 Elements between Sc to Zn 1. All show paramagnetism 2. Form Colored hydrated ion in…

Q: Which of the following complexes do you expect to be (the most) brightly coloured? [Zn(pic)Cl2]…

A: Complex compound which is expected to be (the most) brightly coloured can be found as follows:

Q: Consider Sodium dimethyldithiocarbamate and propose a method to prepare Sodium…

A: Introduction: We have to make Sodium diethyldithiocarbamate.

Q: Write down the IUPAC names of the following complexes and also give stereochemistry and magnetic…

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Q: Which of the following is responsible for the chelate effect exhibited by multidentate ligands? a.…

A: This question is related to coordination Chemistry. Coordination complexes are the molecules in…

Q: Three absorption bands were observed at 11200, 18350, 29000 cm-1 in the electronic spectrum of the…

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Q: If Ksp (AgBr) = 4.0 x 10-¹3, and if, for the Ag+ + NH3 complex system (Ag+ + NH3 ⇒ [AgNH3]*;…

A: Solubility product of sparingly soluble salt is given as the product of concentration of dissolved…

Q: Of the first-row transition metal complexes of formula [M(NH3)6]3+, which metals are predicted by…

A: Concepts of Jahn-Teller distortion.

Q: Which among the following complexes has the highest value of spin magnetic moment?     a.…

A: Spin magnetic moment (s) = √(n(n+2)) n = number of unpaired electron ->As unpaired electron…

Q: Which of the following statements is(are) correct? (1) K; is a measure of the interaction strength…

A: The correct statement is as follows, Kf s the measure of the interaction strength of a ligand…

Q: Jahn-Teller distortions are often encountered with а. octahedral complexes of dº and high o spin d4…

A: Jahn teller distortion occurs in those complexes which has unpaired electron in t2g or eg orbital ie…

Q: Titanium(IV) and vanadium(V) form colored complexes when treated with hydrogen peroxide in 1 M…

A: According to Beer's law, the absorbance of a mixture is sum of each component represented as, A =…

Q: The absorbance values ​​observed during the determination of the complex stoichiometry with the Job…

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Q: Carbonyl stretching in transition metal complexes typically occurs in the region 1700 - 2100 cm1.…

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Q: The M-L distances in tris-(ethylenediamine) complexes of Ru(II) and Ru(III) are 2.12 and 2.10 Å,…

A: Given : The M-L distances in tris-(ethylenediamine) complexes of  Ru(II) - 2.12 A Ru(III) - 2.10 A

Q: Rank the following ions in the weak octahedral field in order of increasing Jahn-Teller effect.…

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Q: 2. Draw the structures of the following coordination complexes. a. Hexaquatitanium(III) bromide b.…

A: Given: coordination complexes To draw: their structures

Q: 5.2.1. = (Kn)(Kn). If he was found to be 2.314 x 10³ dm³ mol, which of the two ligands, H₂0 and NHs,…

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Q: by what percentage does the calculated racah paramater (B) value of 760 differ from the free ion…

A: Calculated value of racah parameter: Bcalculated=760

Q: An unknown solution of the Fe-complex has an absorbance of 0.278. What is the concentration of…

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Q: 19. The association constant of protein X for ligand Y is: 100 micromolar. At what concentration of…

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A: Let's discuss about the mechanism for cis-trans isomerisation in five coordinated transition metal…

Q: What is the LFSE for the [Co(bipy)3]Cl2 complex, knowing that $\Delta$o =  11300 cm-1 and P= 22500…

A: LFSE is the ligand field stabilization energy. For the given complex, Co is in +2 state. A strong…

Q: Explain how many D-d transitions you would theoretically expect in complex ions [Ni(NH3)6]2+,…

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Q: A transition metal ion, M, forms a coloured complex with a monodentate ligand L. Portions of a 0.05…

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Q: Q5. The following isomers were obtained for a cobalt complex. How you would distinguish them with…

A: Only the square planar and octahedral complexes can exhibit cis-trans isomerism.

Q: possible ways in which Cu2+ could sorb to a hematite surface

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Q: The stability of metal complexes with EDTA is due to the formation of: A) Zwitterion B) Chelate…

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Q: An absorbance versus concentration data for the thiocyanatoiron(III) complex at 510 nm and makes a…

A: The given graph at 510 nm for concentration vs absorbance is :

Q: An aqueous solution of sodium hexaiodoplatinate(IV) isblack. What conclusions can be drawn about the…

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Q: The mass speetra g rhodrium carbonyl complex indicate & duriacing every peak at 748 amu, F20 amu 28…

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Q: Show how to use the microanalysis data to determine the number of cod (C8H12) ligands per Pd. C,…

A: Given: Mass percent of Pd = 37.27 % And mass percent of C = 33.65 %

Q: A protein binds a ligand with a KD value of 0.25 M. If you are at a ligand concentration of 0.63 M,…

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Q: Assess the validity of each statement and choose X if the statement is CORRECT, Choose Y if…

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Q: Which of the following is responsible for the chelate effect exhibited by multidentate ligands? Only…

A: The chemical reasons for the chelate effect involve relative enthalpy and entropy changes upon…

Q: The correct systematic name for the complex [Mn(NCS)3(OH₂) (Ox)] is O tris(thiocyanato-KN)…

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Q: 6.) a.) In the series of Werner complexes (after the German-Swiss chemist) [CoX(NH3)s]** with X =l',…

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Q: Write the name of the structure and the magnetic behaviour of each one of the following complexes:…

A: Naming of coordination complexes is done in such a way that name of ligands written first…

Q: Draw structures for the following complexes: fac-triaquacyanidodinitrito-kN-chromate(III) ion…

A:

Q: Provide names for the following complexes: a) Li[Cr(ox)2(OH2)2] b) Na2[PtCl6] c) [Co(en)2Br2]I d)…

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Q: a) Illustrate the transfer of electrons from the ligand to metal ion in hexaaquairon(III) ion,…

A: a) The given complex is hexaaquairon(III) ion, [Fe(H2O)6]+3. The structure of the complex is,