how to get 1-(1-methyl-3,4-dihydro-1H-isoquinolin-2-yl)ethanone from N-ethenyl-N-(2-phenylethyl)acetamide . answer and explain it step by step
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how to get 1-(1-methyl-3,4-dihydro-1H-isoquinolin-2-yl)ethanone from N-ethenyl-N-(2-phenylethyl)acetamide .
answer and explain it step by step
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- how to get 1-(1-methyl-3,4-dihydro-1H-isoquinolin-2-yl)ethanone from N-ethenyl-N-(2-phenylethyl)acetamide answer this step by stepShow the products from reaction of p-bromoaniline with the following reagents: (a) CH3I (excess) (b) HCl (c) HNO2, H2SO4 (d) CH3COCl (e) CH3MgBr (f) CH3CH2Cl, AlCl3 (g) Product of (c) with CuCl, HCl (h) Product of (d) with CH3CH2Cl, AlCl3Show how m-toluidine can be converted tom-toluidineCH3 NH2the following compounds, using any necessary reagents.m-toluonitrile(a) CH3 C N CH3 CH2NH2m-methylbenzylamine(b)m-iodotolueneCH I 3 (c)m-cresol(d) CH3 OH3-methyl-4-nitroanilineCH3 NH2O2N(e)NHCH3N-cyclopentyl-m-toluidine
- p-Nitrobenzaldehyde is more reactive toward nucleophilic additions than p-methoxybenzaldehyde. Explain.Show how to convert racemic ethyl 2-oxocyclopentanecarboxylate to racemic 2-allylcyclopentanone.Draw the product(s) of each of the following reactions: a. benzoic acid + HNO3/H2SO4 b. isopropylbenzene + Cl2 + FeCl3 c. p-xylene + acetyl chloride + AlCl3 followed by H2O d. o-methylaniline + benzenediazonium chloride e. cyclohexyl phenyl ether + Br2 f. phenol + H2SO4 + ∆ g. ethylbenzene + Br2/FeBr3 h. m-xylene + Na2Cr2O7 + HCl + ∆
- What would be the major product if acetophenone (PhCOCH3) was treated with excess I2 and NaOH? A. CHCl3 B. PhCO2 C. PhCO2H D. CH3CO2 E. PhCH2OHShow the products from the reaction of p-bromoaniline with following reagents: a)CH3Cl(excess) b) HCl c) CH3COCl d) CH3MgBr e) CH3CH2Cl, AlCl3Explain why hydroxide ion catalyzes the reaction of piperidine with 2,4-dinitroanisole but has no effect on the reaction of piperidine with 1-chloro-2,4-dinitrobenzene.
- Show how the following compounds can be synthesized from benzene: a. N,N,N-trimethylanilinium iodide b. 2-methyl-4-nitrophenol c. p-benzylchlorobenzene d. benzyl methyl ether e. p-nitroaniline f. m-bromoiodobenzene g. p-dideuteriobenzene h. p-nitro-N-methylaniline i. 1-bromo-3-nitrobenzeneShow how m-toluidine can be converted tom-toluidineCH3 NH2the following compounds, using any necessary reagents.m-toluonitrile(a) CH3 C N CH3 CH2NH2m-methylbenzylamine(b)m-iodotolueneDraw the products of the following reactions: a. diethyl heptanedioate: (1) sodium ethoxide; (2) HCl b. pentanoic acid + PBr3 + Br2, followed by hydrolysis c. acetone + LDA/THF: (1) slow addition of ethyl acetate; (2) HCl d. diethyl 2-ethylhexanedioate: (1) sodium ethoxide; (2) HCl e. diethyl malonate: (1) sodium ethoxide; (2) isobutyl bromide; (3) HCl, H2O + ∆ f. acetophenone + LDA/THF: (1) slow addition of diethyl carbonate; (2) HCl
