How would you prepare the following compounds from 2-phenylethanol? More than one step may be required. (a) Styrene (PHCH=CH2) (b) Phenylacetaldehyde (PHCH2CHO) (c) Phenylacetic acid (PHCH2COOH) (d) Benzoic acid (e) Ethylbenzene (f) Benzaldehyde (g) 1 -Phenylethanol (h) l-Bromo-2-phenylethane

How would you prepare the following compounds from 2-phenylethanol? More than one step may be required. (a) Styrene (PHCH=CH2) (b) Phenylacetaldehyde (PHCH2CHO) (c) Phenylacetic acid (PHCH2COOH) (d) Benzoic acid (e) Ethylbenzene (f) Benzaldehyde (g) 1 -Phenylethanol (h) l-Bromo-2-phenylethane

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter24: Amines And Heterocycles

Section24.8: Reactions Of Arylamines

Problem 18P: How would you prepare the following compounds from benzene, using a diazonium replacement reaction...

See similar textbooks

Related questions

Q: These reagents can produce ketones with alkynes A. BH3, THF, H2O2 B. KMnO4 C. O3 D. H2SO4, H2O,…

Q: How much heat in kilojoules is released when 209.0 g hydrogen bromide (HBr) is dissolved if its…

A: Given: Molar heat of solution = -85.1 kJ/mol Mass of HBr = 209.0 g Known: Molar mass of HBr = 80.91…

Q: Chemistry Give the products of the reaction of 1 mole of 2-methy1-1,3-pentadiene with 1 mole of…

Q: Ca(OH)2 (s) + H2S(g) CaS(s) + 2H2O(1 In the reaction above, calcium hydroxide and hydrogen sulfide…

A: Here we find limiting reagent that is totally react with reactant. Here limiting reagent is Calcium…

Q: An activator molecule like DCC is important to create a good leaving group from a -COOH functional…

A: DCC is named as dicyclohexylcarbodiimide. It is used as a coupling agent in most of the organic…

Q: General Equation Type of Reaction A +X- AX AX A+ X A+ BX → AX +B -or- Y + BX → BY + X AX + BYAY + BX…

Q: For the reaction M9CO3 (s)-MgO (s) + CO2 (g) we can say that it is a reaction; spontaneous not…

Q: The boiling point of an aqueous solution is 101.87 °C. What is the freezing point? Consult the table…

A: Given data : Boiling point of solution = 101.87°C Freezing point constant (Kf) = 1.86 °C.kg/mol…

Q: molecular equation F, (g) + NaCl (aq) – net ionic equation 2. molecular equation K (s) + HBr (aq) →…

Q: shown below: 主 H-O H-C- H H-C. tő-c-H H H-C-9 H-C C-ő -- H H H. Sucrose Mineral Oil Only one of…

A: Here we have to explain the solubility of sucrose in water based upon intermolecular of attraction.

Q: This equation is not balanced. What is the sum of the molar coefficient for the balanced equation?…

Q: 215.0 mol of an unknown gas is stored at a temperature of 1110 K in a large, 395 L container. In…

Q: (References] What will the volume of a sample be if 400. mL of an ideal gas at 23 °C and 1.50 atm is…

Q: The ocean pressure at the depth of the titanic wreck is 40500 kPa. Calculate the ocean pressure in…

Q: Given the reaction: 2 Al (s) + 6 HCI (aq) 2 AICI3 (aq) + 3 H2 (g) A strip of aluminum of unknown…

A: All the required calculations have been done in the following step.

Q: Find the pH of a 0.0025 M HCl solution.

A: pH of a solution = -log[H+]

Q: Consider the reaction 3X + 2Y → 5C + 4D With excess Y, how many moles of X are needed to produce…

Q: Choose the best option for the immediate electrophile precursor to the benzylic alcohol…

Q: 45.0 g of lead (Il) acetate is reacted with 63.0g of ammonium sulfide, how many particles of product…

Q: Chemistry There are 2.55 1015 short tons of oxygen in the atmosphere (1 short ton = 2000 lb). How…

A: Oxygen in the atmosphere = 2.55 × 1015 short tons. 1short ton = 2000 Ib 1metric Ton = 1000 kg…

Q: 1.Two samples of the same soil is subjected to pH analysis using a pH meter, the first is analysed…

A: While measuring the pH of a soil, water or KCl can be used as the diluent.

Q: 1. Draw the best Lewis dot structure for SeF4 in the correct molecular geometry [Include formal…

A: Draw the best Lewis dot structure for SeF4 in the correct molecular geometry [Include formal…

Q: Chemistry write the structure of the major organic compound formed in the boxes OH OH PCC -> CHCL

A: Major product formed in the following reaction = ?

Q: Given the following reaction and the amounts of the reactants, determine the mass (in grams) of…

Q: Please draw the skeletal formula of the following compounds: (A) Isobutyraldehyde (B)…

Q: Chemistry What is the equilibrium concentration of hydroxyl ions present in a solution of HClO4…

A: Given data : Concentration of HClO4 =1.9 M

Q: 5) Below is a list of pros and cons to using aluminum cans vs. plastic bottles. Based on this list,…

A: The objective of the question is to discuss the effectiveness of material Based on the pros and cons…

Q: A solution of a weak acid is titrated with a standard solution of a strong base. The progress of the…

Q: 3. The equilibrium constant K, for the following reaction is 2.18 x 10 at 730 °C. Starting with 3.20…

Q: 17. An organic chemist reacted 10.0 g CH4 with excess Cl2 and obtained 10.0 g of CH3CI according to…

Q: Evaluate (∂S/∂V)T for a van der Waals gas. For an isothermal expansion, will DS be greater for an…

Q: 1/INO,(8)] (1/M) 5. You studied the chemical reaction, 2NO2(g) → 2NO(g) + O2(g), at 25°C by…

A: Rate constant, is a proportionality constant in an equation which depicts the relationship between…

Q: Please write the IUPAC name of the following compounds. Observe proper punctuations. Make sure that…

Q: what is the chemical equation of alkyl dimethyl benzyl ammonium chloride?

Q: Describe the Bohr model of the atom, including quantization and emission spectra. (b) Discuss the…

A: SUCCESSES OF BOHR MODEL = Bohr theory modified the atomic structure model by explaining that…

Q: (s) NAOH EŁOH H, COOEE dietil malonato

Q: Photo is only attached as reference.- What does the mass of the reactants and products tell us about…

Q: Calculate the solubility product constant of silver chromate whose molar solubility is 1.3 10^-4…

Q: Name the following coordination compound below K2[NbF,] H[Mo(CO),Br;] i. ii. iii.…

A: Coordination compound have a metal ion that is bonded to ligands by coordination bonds.…

Q: 15. Which statement is not evidence for the wave-particle duality of light? O Light travels at a…

A: The objects bent when it seen through a galss of water is the refraction property of light only. So…

Q: Chemistry 3. Provide reagents/conditions to accomplish the following syntheses. Several steps are…

A: In this question, we will used the reagents and conditions ( like heating condition or solvent ) for…

Q: If the absolute entropy for O2 (g) is 126 J / (mole K), what is the ΔS for the combustion of…

A: Here we have to determine the change in entropy of combustion of ethene (∆Scomb) .

Q: A high energy bond is formed when ADP is phosphorylated to ATP. Why? Choose all that apply. a) there…

A: a) there is a decrease in entropy. c) the negative charges on ADP and inorganic phosphate repel each…

Q: Given the data, what pressure would the butane gas sample have at a volume of 135.0ml? Please show…

A: According to Boyle's law, at constant temperature(T) and the number of moles of gas(n), the…

Q: Using Appendix II from your textbook and DG°rxn for the reaction below, determine the standard Gibbs…

A: Standard gibbs free energy of formation of urea can be calculated by given DG° is reaction and…

Q: What is the mass in kilograms (kg) of 4.29 X 1024 atoms of palladium?

Q: Draw the curved arrow that explains how the products are formed. Select Draw Rings More Erase ++…

Q: 3. What is the maximum number of p orbitals that can overlap in amphotericin B (2)? How many levels…

Q: Sample student prepares three buffer solutions. Each solution is 1.0 M in one of the acids in the…

A: When NaOH is added to the the buffer solutions , it will react with acidic part of buffer. So the…

Concept explainers

Aromatic Compounds

Aromatic organic compound or aromatic system is an important class of hydrocarbons under the branch of organic chemistry. Aromatic compounds are also called arenas. The definition of aromatic organic compounds can be stated as a class of organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Due to these alternating bonds, a peculiar feature termed as ‘resonance’, that is, delocalization of pi electrons or the electrons is shared within the atoms of the ring which are present in the aromatic compounds. The word ‘aromatic’ includes a Greek word ‘aroma’ which means smell, indicating that they were named as such due to the sweet odor they produce. Many well-known flavors such as vanilla, cinnamon, and few scents from flowers are extracted from aromatic compounds. Benzene with chemical formula C6H6 is a very common aromatic compound that contains six atoms of carbon held in the cyclic ring of alternate double bonds. It is also to be noted that not all aromatic compounds contain benzene ring. This can be explained by Huckel’s rule.

Question

How would you prepare the following compounds from 2-phenylethanol? More than one
step may be required.
(a) Styrene (PHCH=CH2)
(b) Phenylacetaldehyde (PHCH2CHO)
(c) Phenylacetic acid (PHCH2COOH)
(d) Benzoic acid
(e) Ethylbenzene
(f) Benzaldehyde
(g) 1 -Phenylethanol
(h) l-Bromo-2-phenylethane

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Trending now

This is a popular solution!

Step by step

Solved in 4 steps with 3 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Reaction of p-nitroaniline with sodium nitrite and hydrochloric acid at 0°C, followed by treatment with N,N-diethylaniline.
(a) Arrange the following compounds in an increasing order of their indicated property :(i) Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxybenzoic acid (acid strength)(ii) CH3CH2CH (Br) COOH, CH3CH (Br) CH2COOH,(CH3)2CHCOOH, CH3CH2CH2COOH (acid strength)(b) How would you bring about the following conversions :(i) Propanone to Propene (ii) Benzoic acid to Benzaldehyde(iii) Bromobenzene to 1-phenylethanol
A student mixes benzaldehyde with an unknown symmetrical ketone, compound C, in an aqueous sodium hydroxide solution and produces compound D.Based on the 1H NMR of compound D, shown below, predict the structure of compound
Amines are converted into alkenes by a two-step process called Hofmann elimination. SN2 reaction of the amine with an excess of CH3I in the first step yields an intermediate that undergoes E2 reaction when treated with silver oxide as base. Pentylamine, for example, yields 1-pentene. Propose a structure for the intermediate, and explain why it readily undergoes elimination.
Why do you suppose only symmetrical ethers are prepared by the sulfuric-acid-catalyzed dehydration procedure? What product(s) would you expect if ethanol and 1-propanol were allowed to react together? In what ratio would the products be formed if the two alcohols were of equal reactivity?
How would you prepare the following compounds from benzene, using a diazonium replacement reaction in your scheme? (a) p-Bromobenzoic acid (b) m-Bromobenzoic acid (c) m-Bromochlorobenzene (d) p-Methylbenzoic acid (e) 1, 2, 4-Tribromobenzene
A. In the synthesis of 1-bromobutane, what is the inorganic by-product left in the reaction flask following the distillation? Why was the bromoalkane the bottom layer in the separatory funnel? B. Predict the product when 1-methylcyclohexanol reacts with H2SO4 and KBr. Show the mechanism.
Diethyl carbonate serves as a less-toxic alternative to phosgene for making Lexan. Propose a mechanism for the transesterification of diethyl carbonate with bisphenol A, catalyzed by a trace of sodium ethoxide. What small molecule is given off in this condensation?
Reaction of N,N-diethyl-p-diaminobenzene with sodium nitrite and hydrochloric acid at 0°C, followed by treatment with nitrobenzene.
Give reagents necessary and show isolated intermediates for the synthesis below.
Which one of the following compounds gives 5-methyl-3-heptanol with LiAlH4 followed by water?
How would you prepare the following compounds from 2-phenylethanol? More than one step may be required.