How would you synthesize the following alcohols, starting with benzene and other alcohols of six or fewer carbons as your only organic reagents? (b) OH (a) (c) CH₂CH3 HO CH3 CH₂CH₂CH3 CH3 CH3CH₂CH₂CHCH₂CH₂OH (d) CH3 OH CH3CHCH₂CHCH₂CH3

How would you synthesize the following alcohols, starting with benzene and other alcohols of six or fewer carbons as your only organic reagents? (b) OH (a) (c) CH₂CH3 HO CH3 CH₂CH₂CH3 CH3 CH3CH₂CH₂CHCH₂CH₂OH (d) CH3 OH CH3CHCH₂CHCH₂CH3

Introduction to General, Organic and Biochemistry

11th Edition

ISBN:9781285869759

Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Chapter17: Aldehydes And Ketones

Section: Chapter Questions

Problem 17.37P

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Concept explainers

Aromatic Compounds

Aromatic organic compound or aromatic system is an important class of hydrocarbons under the branch of organic chemistry. Aromatic compounds are also called arenas. The definition of aromatic organic compounds can be stated as a class of organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Due to these alternating bonds, a peculiar feature termed as ‘resonance’, that is, delocalization of pi electrons or the electrons is shared within the atoms of the ring which are present in the aromatic compounds. The word ‘aromatic’ includes a Greek word ‘aroma’ which means smell, indicating that they were named as such due to the sweet odor they produce. Many well-known flavors such as vanilla, cinnamon, and few scents from flowers are extracted from aromatic compounds. Benzene with chemical formula C6H6 is a very common aromatic compound that contains six atoms of carbon held in the cyclic ring of alternate double bonds. It is also to be noted that not all aromatic compounds contain benzene ring. This can be explained by Huckel’s rule.

Question

17-45 How would you synthesize the following alcohols, starting with benzene
and other alcohols of six or fewer carbons as your only organic reagents?
(a)
(b)
(c)
OH
CH₂CH3
HO CH3
CH₂CH₂CH3
CH3
CH3CH₂CH₂CHCH₂CH₂OH
(d) CH3 OH
CH3CHCH₂CHCH₂CH3

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