Hydrogen can be produced commercially by reforming methanol with steam, depending on the reactionCH3OH(g) + H2O (g) ---> CO2(g) + 3H2(g) a) Find the value of AH0 for this reaction using the data fromAppendix A. b) Determine the AH0 of the reaction using the data in the appendixA. c) Find the AH0 of this reaction at 100 ° C. (Assume that ASO and AH0 do not vary with temperature). Is the reaction spontaneous at 100°C? d) Find the KP value for this reaction at 100 oC.

Chemistry: An Atoms First Approach
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Chapter16: Spontaneity, Entropy, And Free Energy
Section: Chapter Questions
Problem 16Q: Consider the following potential energy plots: a. Rank the reactions from fastest to slowest and...
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Data Appendice A (second picture)
Hydrogen can be produced commercially by
reforming methanol with steam, depending
on the reactionCH3OH(g) + H2O (g) --->
CO2(g) + 3H2(g)
a) Find the value of AH0 for this reaction
using the data fromAppendix A.
b) Determine the AH0 of the reaction using
the data in the appendixA.
c) Find the AH0 of this reaction at 100 ° C.
(Assume that ASO and AH0 do not vary with
temperature). Is the reaction spontaneous at
100°C?
d) Find the KP value for this reaction at 100
ОС.
AH®, (kJ-mol) S° (J K' mol)
-171,2
-181,5
-986,1
molécule
Br(aq)
CaH2(s)
Ca(OH)2(s)
H:(g)
H2O(1)
H;O(g)
H2S(g)
H2S(aq)
HC(g)
HCl(aq)
CO(g)
CO:(g)
COC:(g)
CH(g)
CH,OH(1)
CH:OH(g)
CH;CH>OH(1)
CH;CH>OH(g)
CS:(g)
Hg²"(aq)
HgCl:(s)
|Mg(s)
Mg(OH):(s)
NaOH(s)
NaOH(aq)
O:(g)
Pb (aq)
PbBr:(s)
SO:(g)
SO (g)
33,8
41,4
83,4
130,6
-285,8
-241,8
-20,2
69,9
188,7
205,6
-39
122
-92,31
-167,159
-110,5
-393,5
186,2
56,5
197,8
213,6
283,53
186,2
127.2
-74,9
| -238,4
-201
-277
239.9
160,7
282,7
237,79
-32,2
146
32,67
63,18
64,5
48,2
205,0
34,2
42
248,1
256,6
-235
117
171,1
-224
-924,54
425,6
470,1
168,2
-225
-296,8
-395,7
Transcribed Image Text:Data Appendice A (second picture) Hydrogen can be produced commercially by reforming methanol with steam, depending on the reactionCH3OH(g) + H2O (g) ---> CO2(g) + 3H2(g) a) Find the value of AH0 for this reaction using the data fromAppendix A. b) Determine the AH0 of the reaction using the data in the appendixA. c) Find the AH0 of this reaction at 100 ° C. (Assume that ASO and AH0 do not vary with temperature). Is the reaction spontaneous at 100°C? d) Find the KP value for this reaction at 100 ОС. AH®, (kJ-mol) S° (J K' mol) -171,2 -181,5 -986,1 molécule Br(aq) CaH2(s) Ca(OH)2(s) H:(g) H2O(1) H;O(g) H2S(g) H2S(aq) HC(g) HCl(aq) CO(g) CO:(g) COC:(g) CH(g) CH,OH(1) CH:OH(g) CH;CH>OH(1) CH;CH>OH(g) CS:(g) Hg²"(aq) HgCl:(s) |Mg(s) Mg(OH):(s) NaOH(s) NaOH(aq) O:(g) Pb (aq) PbBr:(s) SO:(g) SO (g) 33,8 41,4 83,4 130,6 -285,8 -241,8 -20,2 69,9 188,7 205,6 -39 122 -92,31 -167,159 -110,5 -393,5 186,2 56,5 197,8 213,6 283,53 186,2 127.2 -74,9 | -238,4 -201 -277 239.9 160,7 282,7 237,79 -32,2 146 32,67 63,18 64,5 48,2 205,0 34,2 42 248,1 256,6 -235 117 171,1 -224 -924,54 425,6 470,1 168,2 -225 -296,8 -395,7
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