The reversible elementary reaction takes place as follows:kfA+B7k,PBy performing the temperature-jump experiment, the relaxationtime is measured as 310 us in the equilibrium state where theequilibrium constant is 0.7 and the equilibrium concentration ofP is 0.2 M. What are the rate constants for forward and reversereactions?

The reversible elementary reaction given here Given Relaxation time 310 * 10-6 s K= kf/kb = 0.7…

Answered: The reversible elementary reaction…

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter11: Chemical Kinetics

Section: Chapter Questions

Problem 80E

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The reversible elementary reaction takes place as follows:
kf
A+B7
k,
P
By performing the temperature-jump experiment, the relaxation
time is measured as 310 us in the equilibrium state where the
equilibrium constant is 0.7 and the equilibrium concentration of
P is 0.2 M. What are the rate constants for forward and reverse
reactions?

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I don't understand how we wrote the ratio values directly as Kf and Kb. In fact, I did not understand how the 1st equality was passed directly to the A equation molarity. I think this solution is wrong.

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