i) Provide curly arrows describing both the forward and backward reactions for the ionisation of propanoic acid in water (see below). CO,H H20 H30 ii) The pKa value for this equilibrium process at 25 °C is 4.8. Using an equation show how this value relates to K, and use this information to comment on the acidity of carboxylic acids compared to hydrochloric acid (pK, = -7). ii) Predict whether substituted propanoic acids A and B are more, or less acidic than propanoic acid. Explain briefly your reasoning. A в CO,H CO2H

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter15: Principles Of Chemical Reactivity: Equilibria
Section15.6: Disturbing A Chemical Equilibrium
Problem 2.2ACP
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(i)
Provide curly arrows describing both the forward and backward reactions for the ionisation of
propanoic acid in water (see below).
`CO2H
+ H2O
H30
(ii) The pka value for this equilibrium process at 25 °C is 4.8. Using an equation show how this
value relates to Ka and use this information to comment on the acidity of carboxylic acids
compared to hydrochloric acid (pK, = -7).
(ii) Predict whether substituted propanoic acids A and B are more, or less acidic than propanoic
acid. Explain briefly your reasoning.
CI
A
B
CO,H
`CO2H
Transcribed Image Text:(i) Provide curly arrows describing both the forward and backward reactions for the ionisation of propanoic acid in water (see below). `CO2H + H2O H30 (ii) The pka value for this equilibrium process at 25 °C is 4.8. Using an equation show how this value relates to Ka and use this information to comment on the acidity of carboxylic acids compared to hydrochloric acid (pK, = -7). (ii) Predict whether substituted propanoic acids A and B are more, or less acidic than propanoic acid. Explain briefly your reasoning. CI A B CO,H `CO2H
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