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Fundamentals Of Analytical Chemistry

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter31: Introduction To Analytical Separations

Section: Chapter Questions

Problem 31.21QAP

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Identify all of the conditions that would facilitate the following conversion.
>
CI
AICI3
1.
, AICI 3
2. NaBH4, MeOH
1.
CI
AICI 3
2. NaBH, MeOH
1.
Cl
, AICI 3
2. Zn(Hg). HCI
1.
, AICI 3
2. Zn(Hg), HCI
only product
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Please answer this NEATLY, COMPLETELY, and CORRECTLY for an UPVOTE. CuSO4From the stock solution (0.040 M), pipet 0.00, 2.00, 5.00, 10.00, 15.00 and 20.00 aliquots into 100 mL volumetric flasks. Develop the color (royal blue) by adding enough NH3 solution to form Cu(NH3)42+ complex. Add 10 mL excess to stabilize to complex. Dilute to the desired volume. Determine the concentration of each standard solution and tabulate. *I'm not sure if a Dilution Factor (DF) is still needed in here but I hope you can also explain this if DF is still needed in the computation.
Please answer this NEATLY, COMPLETELY, and CORRECTLY for an UPVOTE. CuSO4From the stock solution (0.040 M), pipet 0.00, 2.00, 5.00, 10.00, 15.00 and 20.00 aliquots into 100 mL volumetric flasks. Develop the color (royal blue) by adding enough NH3 solution to form Cu(NH3)42+ complex. Add 10 mL excess to stabilize to complex. Dilute to the desired volume. Determine the concentration of each standard solution and tabulate.
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Sudies have revealed extremely high deposits of heavy metals and paryiculate matterin rivers , making them unwholesome for drinking. With your on analytical separation and analyses, outline a suitable analytical separation protocol that can be employed to recover polluted river bodies and make wholesome for drinking. Explain in details.
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John wanted to determine the protein content of his blood. To do so, he obtained 1.00 mLof blood, and diluted it to 10.00 mL. From that solution, he subjected 1.00 mL to Kjeldahl analysis. After digestion, the liberated NH3 was distilled in a flask containing exactly 25.00 mL of 0.0150 M H3BO3. Titration requires 5.85 mL of standard 0.0150 M NaOH to reach the desired endpoint. If a typical blood sample contains 15.45 g N per 100 g protein, calculatethe protein content (in g/mL) in the sample of John’s blood.
A suitable target for the titration is 30.0 cm3 of 0.025 moldm-3 Br2(aq) Justify why a much smaller target titre would not be appropriate Calculate the amount in moles of bromine in the target titer Justification? calculate a suitable massof alive oil to transfer to the volumetric flask using your answer to of above question and the structure of Y Assume that the olive oil contains 85/- of Y by mass (If you were unable to calculate the amount of bromine in the target titer,you should assume it is 6.25×10^-8 mol .this in not the correct amount)
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A. This is the equilibrium constant for the reactionin which a solid salt dissolves to give its constituent ions in Chemicalequilibrium constant Solubilityproduct constant Idealgas constant Noneof these B. Directprecipitimetry: Van’tHoff Method VolhardMethod MohrMethod Gay-LussacMethod C. Molecules which provide a group ofattachments used in Maskingagents Demaskingagents Ligands Chelatingagents D. Substances that determine the concentrationof a metal in the presence of another metal Maskingagents Demaskingagents Ligands Chelatingagents E. EDTAis an example of a: Masking agent Demaskingagent Ligand Chelatingagent For numbersF to H, identify the component of the chemical reaction: PO4-3 + H3O+ → HPO4-2 + H2O. Select from the following choices: Acid Base Conjugateacid Conjugatebase F. PO4-3 G. HPO4-2 H. H2O For numbers I to L, consider the given chemical equation: NH3(aq) + H2O(l) ↔ NH4+(aq) + OH-(aq) I Thechemical reaction from the given…

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