If a compound has a molecular ion with an odd-numbered mass, then the compound contains an odd number of nitrogen atoms. This is known as the nitrogen rule.a. Calculate the m/z value for the molecular ion of each of the following compounds:b. Explain why the nitrogen rule holds.c. State the rule in terms of a molecular ion with an even-numbered mass. If a compound has a molecular ion with an odd-numbered mass, then the compound contains an odd numberof nitrogen atoms. This is known as the nitrogen rule.a. Calculate the mlz value for the molecular ion of each of the following compounds:1.`NH,2. НN`NH2b. Explain why the nitrogen rule holds.c. State the rule in terms of a molecular ion with an even-numbered mass.

Answered: If a compound has a molecular ion with…

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter14: Mass Spectrometry

Section: Chapter Questions

Problem 14.7P: The so-called nitrogen rule states that if a compound has an odd number of nitrogen atoms, the value...

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If a compound has a molecular ion with an odd-numbered mass, then the compound contains an odd number of nitrogen atoms. This is known as the nitrogen rule.
a. Calculate the m/z value for the molecular ion of each of the following compounds:

b. Explain why the nitrogen rule holds.
c. State the rule in terms of a molecular ion with an even-numbered mass.

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