If the reaction of an alcohol with PB13 follows an SN2 mechanism, what is the stereochemistry of the alkyl bromide formed from (2R)-2-butanol?
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- Consider a reaction where cis-but-2-ene is treated with a peroxy acid followed by OH- /H20. Draw the structure of one product that is formed in the reaction, including correct stereochemistry.What stereoisomers are obtained when (S)-3-methyl-1-pentene reacts with Cl2?The reaction of 1-bromopropane and sodium hydroxide in ethanol occurs by an SN2 mechanism. What happens to the rate of this reaction under the following conditions? Q.) The concentration of NaOH is doubled.
- Account for the regioselectivity and stereoselectivity observed when 1-methylcyclopentene is treated with reagent Q.Hg(OAc)2 in H2ODescribe the stereochemistry of the bromohydrin formed in each reaction (each reaction is stereospecific). (a) cis-3-Hexene + Br2/H2O (b) trans-3-Hexene + Br2/H2O1,2 addition of Br2 to an alkene results in a _______________. A. alcohol B. vicinyl dihalide C. alkyl halide D. geminal dihalide
- Draw the SNl or SN2 reaction with CN for the following molecules t butylchloride , n - butylbromide , 2 -bromobutane . Explain in which mechanism it will react and why ?Account for the regioselectivity and stereoselectivity observed when 1-methylcyclopentene is treated with reagent. Q) Br2 in H2OPrimary and secondary alcohols can be converted to alkyl bromides via treatment with PBr3. The reaction proceeds via an SN2 mechanism with inversion of configuration at the chiral carbon.Draw curved arrows to show the movement of electrons in this step of the mechanism.
- Consider a reaction where cis-but-2-ene is treated with OsO4 followed by NaHSO3/H2O. Draw the structure of one product that is formed in the reaction, including correct stereochemistry.Primary and secondary alcohols can be converted to alkyl chlorides via treatment with thionyl chloride. The reaction proceeds via an SN2 mechanism with inversion of configuration at the chiral carbon.Draw curved arrows to show the movement of electrons in this step of the mechanism.Treatment of cis-2-bromocyclohexanol with NaOH yields cyclohexanone instead of an epoxide. Draw curved arrows to show the movement of electrons in this step of the reaction mechanism.