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- Q3: What products would you expect from the reaction of 1-bromopropane with each of the following?(a)NaNH2 (b) KOC(CH3)3 (c) Nal(d) NaCN (e) NaC=CH (f) Mg, then H2OWhat is the expected major product of reacting cyclohexane carbaldehyde with (CH3)2NH?Draw all products of the reaction of (1S,2R)-1-bromo-1,2-dimethylcyclohexane in 80%H2O/20%CH3CH2OHat room temperature..
- What is the major product of the reaction of 2-methyl-2-butene with each of the following reagents? a. HBr b. HI c. Cl2/CH2Cl2 d. O3, −78 °C, followed by (CH3)2S e. H2/Pd f. MCPBA (a peroxyacid) g. H2O + H2SO4 h. Br2/CH2Cl2i. Br2/H2O j. Br2/CH3OH k. BH3 /THF, followed by H2O2, HO-, H2OWhich will complete the following reactions? Choices: A. HBr / ether B. PBr3 / ether C. SOCl2 / pyridine D. Br2 / NBS E. Chlorocyclopentane F. Cyclopentanol G. IodobenzeneWhat is the expected major product of reacting cyclohexane carbaldehyde jwith CH3NH2?
- Cyclohexene plus 1) Hg(OAc)2, H2O; 2) NaBH4; yields __________. HO2CCH2CH2CH2CH2CO2H a cyclic diketone cyclohexyne cyclohexanol OHCCH2CH2CH2CH2CHOWhat products would from when 4-methylbenzaldehyde reacts with the following? (a) CH3CHO, OH- (b) CH3C CNa, then H3OAs a rule, axial alcohols oxidize somewhat faster than equatorial alcohols. Which would you expect to oxidize faster, cis-4-tert-butylcyclo-hexanol or trans-4-tert-butylcyclohexanol? Draw the more stable chair conformation of each molecule.
- How would you synthesize the following compounds from cyclohexanone? a) 1Methylcyclohexene b) 2Phenvlcyclohexanone c) cis1, 2Cyclohexanediol d) 1CyclohexylcyclohexanolThe following reactivity order has been found for the saponification of alkyl acetates by aqueous NaOH. Explain. CH3CO2CH3 > CH3CO2CH2CH3 > CH3CO2CH(CH3)2 > CH3CO2C(CH3)3The acid-catalyzed dehydration of 1-methylcyclohexanol yields a mixture of two alkenes. How could you use 1H NMR to help you decide which was which?