In a study of the decomposition of ammonia on a tungsten surface at 1100 °C NH31/2 N2 + 3/2 H2 the following data were obtained: [NH3], M 1.31×10-2 6.55×10-3 3.28×10-3 1.64×10-3 seconds 0 441 661 771 Hint: It is not necessary to graph these data. FILL IN THE BLANKS (1) The observed half life for this reaction when the starting concentration is 1.31×10-2 M is ________s and when the starting concentration is 6.55×10-3 M is ________s. (2) The average rate of disappearance of NH3 from t = 0 s to t = 441 s is ______M s-1. (3) The average rate of disappearance of NH3 from t = 441 s to t = 661 s is __________M s-1. (4) Based on these data, the rate constant for this _______ (zerofirstsecond) order reaction is _____M s-1.

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter11: Rate Of Reaction
Section: Chapter Questions
Problem 52QAP: For the zero-order decomposition of ammonia on tungsten NH3(g) W 12 N2(g)+32 H2(g)the rate constant...
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In a study of the decomposition of ammonia on a tungsten surface at 1100 °C

NH31/2 N2 + 3/2 H2

the following data were obtained:

[NH3], M 1.31×10-2 6.55×10-3 3.28×10-3 1.64×10-3
seconds 0 441 661 771



Hint: It is not necessary to graph these data. FILL IN THE BLANKS

(1)
The observed half life for this reaction when the starting concentration is 1.31×10-2 M is ________s and when the starting concentration is 6.55×10-3 M is ________s.

(2)
The average rate of disappearance of NH3 from t = 0 s to t = 441 s is ______M s-1.

(3)
The average rate of disappearance of NH3 from t = 441 s to t = 661 s is __________M s-1.

(4)
Based on these data, the rate constant for this _______ (zerofirstsecond) order reaction is _____M s-1.

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