In a study of the decomposition of ammonia on a platinum surface at 856 °C NH31/2 N2 + 3/2 H2 the following data were obtained: NH3). M 1.20x10-3 997 3.00x104 1.75x103 2.39x10-3 6.00x104 1.50x103 seconds Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 2.39×10-3 M is s and when the starting concentration is 1.20x103 M is | (2) The average rate of disappearance of NH3 from t= 0s to t= 997 s is Ms! (3) The average rate of disappearance of NH3 from t= 997 s to t= 1.50×103 s is s!. (4) Based on these data, the rate constant for this | order reaction is

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter30: Capillary Electrophoresis, Electrochromatography, And Field-flow Fractionation
Section: Chapter Questions
Problem 30.9QAP
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In a study of the decomposition of ammonia on a platinum surface at 856 °C
NH31/2 N2 + 3/2 H2
the following data were obtained:
NH3], M
2.39x10-3
1.20×103
997
6.00x104
1.50x103
3.00x10-4
1.75x103
seconds
Hint: It is not necessary to graph these data.
(1)
The observed half life for this reaction when the starting concentration is 2.39x10-3 M is
s and when the starting concentration is 1.20×10-3 M is
s.
(2)
The average rate of disappearance of NH3 from t= 0 s to t= 997 s is
Ms!.
(3)
The average rate of disappearance of NH3 from t= 997 s to t= 1.50×103 s is
M
s-l.
(4)
Based on these data, the rate constant for this
| order reaction is
M
s-1.
Transcribed Image Text:In a study of the decomposition of ammonia on a platinum surface at 856 °C NH31/2 N2 + 3/2 H2 the following data were obtained: NH3], M 2.39x10-3 1.20×103 997 6.00x104 1.50x103 3.00x10-4 1.75x103 seconds Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 2.39x10-3 M is s and when the starting concentration is 1.20×10-3 M is s. (2) The average rate of disappearance of NH3 from t= 0 s to t= 997 s is Ms!. (3) The average rate of disappearance of NH3 from t= 997 s to t= 1.50×103 s is M s-l. (4) Based on these data, the rate constant for this | order reaction is M s-1.
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