In an insulated bomb calorimeter, 0.568 g of solid citric acid (C6H8O7, molar mass 192.12 g) was completely combusted, at 25.00 °C. The calorimeter contained 1032 g of water, initally at 25.00°C. The temperature of the water was observed to rise to 26.36 °C. Assume all the heat of the reaction went into heating the water, and that the heat capacity of water is 4.184 J/g-K. Calculate the molar energy change (in kJ mol-1) for combustion of citric acid. -587 O-29.2 -11.3 -484 D-1990

In an insulated bomb calorimeter, 0.568 g of solid citric acid (C6H8O7, molar mass 192.12 g) was completely combusted, at 25.00 °C. The calorimeter contained 1032 g of water, initally at 25.00°C. The temperature of the water was observed to rise to 26.36 °C. Assume all the heat of the reaction went into heating the water, and that the heat capacity of water is 4.184 J/g-K. Calculate the molar energy change (in kJ mol-1) for combustion of citric acid. -587 O-29.2 -11.3 -484 D-1990

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter7: Chemical Energy

Section: Chapter Questions

Problem 100AE

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When one mol of KOH is neutralized by sulfuric acid, q=56 kJ. (This is called the heat of neutralization.) At 23.7C, 25.0 mL of 0.475 M H2SO4 is neutralized by 0.613 M KOH in a coffee-cup calorimeter. Assume that the specific heat of all solutions is 4.18J/gC, that the density of all solutions is 1.00 g/mL, and that volumes are additive. (a) How many mL of KOH is required to neutralize H2SO4? (b) What is the final temperature of the solution?
The enthalpy of combustion of diamond is -395.4 kJ/mol. C s, dia O2 g CO2 g Determine the fH of C s, dia.
9.102 A runner generates 418 kJ of energy per kilometer from the cellular oxidation of food. The runner's body must dissipate this heat or the body will overheat. Suppose that sweat evaporation is the only important cooling mechanism. If you estimate the enthalpy of evaporation of water as 44 kJ/mol and assume that sweat can he treated as water, describe how you would estimate the volume of sweat that would have to be evaporated if the runner runs a 10-km race.
What is the change in internal energy when a gas contracts from 377mL to 119mLundera pressure of 1550 torr, whileat the same time being cooled by removing 124.0J ofheat energy?
In a coffee-cup calorimeter, 150.0 mL of 0.50 M HCI is added to 50.0 mL of 1.00 M NaOH to make 200.0 g solution at an initial temperature of 48.2C. If the enthalpy of neutralization for the reaction between a strong acid and a strong base is 56 kJ/mol, calculate the final temperature of the calorimeter contents. Assume the specific heat capacity of the solution is 4.184 J/g C and assume no heat Joss to the surroundings.
One of the components of jet engine fuel is n-dodecane, C12H26(), which has a standard enthalpy of combustion of 8080.1 kJ/mol. (a) Write the thermochemical equation for the combustion of n-dodecane. (b) Use the standard enthalpies of formation in Appendix G to calculate the standard enthalpy of formation of n-dodecane.
The head of a strike anywhere match contains tetraphosphorus trisulfide, P4S3. In an experiment, a student burned this compound in an excess of oxygen and found that it evolved 3651 kJ of heat per mole of P4S3 at a constant pressure of 1 atm. She wrote the following thermochemical equation: P4S3(s)+8O2(g)P4O10(s)+3SO2(g);H=3651kJ Calculate the standard enthalpy of formation of P4S3, using this students result and the following standard enthalpies of formation: P4O10(s), 3009.9 kJ/mol; SO2(g), 296.8 kJ/mol. How does this value compare with the value given in Appendix C?
When 50.0 g of 0.200 M NaCl(aq) at 24.1 C is added to 100.0 g of 0.100 M AgNO3(aq) at 24.1 C in a calorimeter, the temperature increases to 25.2 C as AgCl(s) forms. Assuming the specific heat of the solution and products is 4.20 J/g C, calculate the approximate amount of heat in joules produced.
Microwave ovens convert radiation to energy. A microwave oven uses radiation with a wavelength of 12.5 cm. Assuming that all the energy from the radiation is converted to heat without loss, how many moles of photons are required to raise the temperature of a cup of water (350.0 g, specific heat =4.18J/gC) from 23.0C to 99.0C?
A sample of ethanol, C2H5OH, weighing 2.84 g was burned in an excess of oxygen in a bomb calorimeter. The temperature of the calorimeter rose from 25.00C to 33.73C. If the heat capacity of the calorimeter and contents was 9.63 kJ/C, what is the value of q for burning 1.00 mol of ethanol at constant volume and 25.00C? The reaction is C2H5OH(l)+3O2(g)2CO2(g)+3H2O(l) Is q equal to U or H?

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