In step 7, a hydroperoxide ion reacts with the glycosulose molecule to form a peroxy intermediate. vii. Draw the 2 arrows of this step. Step 7 is a nucleophilic attack. Why is the glycosulose attractive to nucleophiles like the hydroperoxide viii. ion?

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter26: Aldol And Claisen Reactions
Section: Chapter Questions
Problem 24E
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ONLY ANSWER vii and viii

Hydroperoxide ion
product of STEP
6-b
Glycosulose product of
STEP 5
STEP 7
peroxy intermediate
In step 7, a hydroperoxide ion reacts with the glycosulose molecule to form a peroxy intermediate.
vii.
Draw the 2 arrows of this step.
viii.
Step 7 is a nucleophilic attack. Why is the glycosulose attractive to nucleophiles like the hydroperoxide
ion?
Transcribed Image Text:Hydroperoxide ion product of STEP 6-b Glycosulose product of STEP 5 STEP 7 peroxy intermediate In step 7, a hydroperoxide ion reacts with the glycosulose molecule to form a peroxy intermediate. vii. Draw the 2 arrows of this step. viii. Step 7 is a nucleophilic attack. Why is the glycosulose attractive to nucleophiles like the hydroperoxide ion?
ene-diolate ion
STEP S
hydride produet of
STEP 5
glycosulose fom
BLUE, MB
hydroperoxide ion
STEP 6-b
STEP 6-a
Hydroperoxide ion
product of STEP
6-b
COLORLESS, MBH
Glycosulose product of
STEP5
STEP 7
[3] Draw the 3 arrows showing how STEP 6-a has a hydride attack the BLUE, MB* turning it a COLORLESS,
MBH form of methylene blue
V.
[2] step 6-b reverts MBH back to MB" as it reacts with o, gas. Determine between Step 6-a and Step 6-b
which was a reduction and which was an oxidation process for methylene blue.
vi.
Step 6-a was a
Step 6-b was a
Transcribed Image Text:ene-diolate ion STEP S hydride produet of STEP 5 glycosulose fom BLUE, MB hydroperoxide ion STEP 6-b STEP 6-a Hydroperoxide ion product of STEP 6-b COLORLESS, MBH Glycosulose product of STEP5 STEP 7 [3] Draw the 3 arrows showing how STEP 6-a has a hydride attack the BLUE, MB* turning it a COLORLESS, MBH form of methylene blue V. [2] step 6-b reverts MBH back to MB" as it reacts with o, gas. Determine between Step 6-a and Step 6-b which was a reduction and which was an oxidation process for methylene blue. vi. Step 6-a was a Step 6-b was a
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