1. Why is "A" the major acetal formed when d-erythrose reacts with H2SO4 and acetone?

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter22: Organic Chemistry And Biochemistry
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1. Why is "A" the major acetal formed when d-erythrose reacts with H2SO4 and acetone?

 

2. Why do carbons 2 and 3 on molecule "A" react  with H2SO4 and acetone to form acetal "B", rather than carbons 3 and 4 on molecule "A" forming a different acetal?

D-erythrose
А
В
H
OH
H
H.
t
H
OH
CH3
CH3
H
CH3
CH3
OH
Transcribed Image Text:D-erythrose А В H OH H H. t H OH CH3 CH3 H CH3 CH3 OH
В
H•
H
OH
CH3
H.
H
Он
CH3
но
H
но
H3C
H3C
A
Transcribed Image Text:В H• H OH CH3 H. H Он CH3 но H но H3C H3C A
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