In synthesizing primary (1°) amines by alkylation of NH3, explain how we can prevent the formation of 2° and 3° amines as by-products? You can give an example to help you in explaining but it is not required. (please provide clear and complete explination

In synthesizing primary (1°) amines by alkylation of NH3, explain how we can prevent the formation of 2° and 3° amines as by-products? You can give an example to help you in explaining but it is not required. (please provide clear and complete explination

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter19: Aldehydes And Ketones: Nucleophilic Addition Reactions

Section19.SE: Something Extra

Problem 50MP

See similar textbooks

Related questions

Q: Chemistry An aquifer contaminated with petroleum is found to have the following component…

A: The age of the spill can be evaluated with the help of the BTEX ratio. 'B' implies benzene, 'T'…

Q: Write the correct equilibrium constant for the following reaction. 1.) C2H2(g) + 2H2(g) C2H6(g) 2.)…

Q: The reaction of an aldehyde with an amine gives an imine, which upon reaction with the ketone below…

A: Mannich reaction: Amino alkylation reaction of an alpha acidic proton of a ketone with formaldehyde…

Q: 3. For a generic acid (HA) pK, = 6.3. In what form would the acid exist as primarily at pH 8? In…

A: Here we are required to find the form in which the acid exist at different pH .

Q: What is the correct name for the following compound? Br (R)-3-bromo-3-methoxyprop-1-ene…

Q: Carboxylic acid Draw the condensed formula of the following compounds: 1.…

A: Given compounds are : 1. 2-hydroxy-6-methylheptanoic acid2. b-bromocaproic acid3. 4-chlorobutanoic…

Q: Name and classify each compound a. CH3CH₂CH₂NH2 CH₂CH₂NCH b. CH₂ C. CH3CH₂NHCH2CH3 d. CH3CH₂CH2NHCH3

A: IUPAC nomenclature of amine: Name and Identify the longest chain of carbon bonded to the nitrogen…

Q: Identify if the following system will form a buffer or not. a. HClO3 – NaClO3 b. HCOOH – Ca(HCOO)2

Q: ) What is the highest possible degeneracy of a vibration of a Cr(CO), molecule? Explain your answer.

Q: O 1. of volls NaO 2. HCI, A

A: In this question, we need to draw the reaction mechanism and also draw the major product for this…

Q: Arrange the following atoms in order from smallest to largest radius. Mg N Cs F Ca P

Q: et all that apply For molecules with similar molecular weights, the dispersion foroes become…

A: Dispersion forces are dependent on the molecular weight of the molecule so If the molecular weight…

Q: HEAT + N204 = 2NO2 if the temperature increased, what would be the effect on the equilibrium? also…

Q: For each reaction below, write the conventional, ionic, and net ionic equation. Include designation…

A: Given, Hydroiodic acid reacts with a solution of ammonium sulfite, and Solid nickel…

Q: Be sure to answer all parts. Draw the structure corresponding to each IUPAC name. a.…

Q: Using the reactivity of the various families in the periodic table, which of the following species…

Q: a) Given the Fischer projection for D-ribose below, draw the structure of 8-0-ibofuranose -OH -OH…

Q: The mass defect in the formation of an alpha particle from two protons and two neutrons is 0.0305…

A: 1 kg = 1000 g 0.0305 g/mol *1 kg/1000 g = 3.05*10-5 kg/mol

Q: Please give me discussion for each and every polymeric membrane. Cellulose acetate (CA)…

A: As per the definition, the polymeric membrane is a thin, semipermeable barrier between two gaseous…

Q: What is the electron configuration of Zr? * 1s 2s 2p 3s 3p 4s² 3d ¹0 4p5 5s² 4d² O A 1s² 3s²3 3d20…

Q: A student properly sets up a column chromatography experiment. Although the mixture is soluble in…

A: Column chromatography is used to separate or purify different materials.This colomn chromatography…

Q: 3. For a generic acid (HA) pK, = 6.3. In what form would the acid exist as primarily at pH 8? In…

Q: Complete the following nuclear reaction. 249 Cf+1¹C → 98 Refer your answer to the following Periodic…

Q: What volume of oxygen, measured at 35 degrees Celsius and 850 mm Hg is required to burn 4.54…

A: Since you have asked multiple question, as per our company guidelines we are supposed to answer the…

Q: When the blood pH begins to rise, O less CO₂ is exhaled. Omore carbonic acid is excreted. more…

A: pH of solution is defined as negative logarithm of hydrogen

Q: Direction: Write the oxidation half-reaction and reduction half-reaction, and shorthand…

Q: What effect does element size have on acidity?

A: There is significant effect of element size on acidity. With increasing size of atom acidity…

Q: О NaOCH3 НО

A: In this question, we need to explain why this reaction not occur. In this reaction three member…

Q: Select the other modes of AAS * Atomic Emission Direct Flame Nitrous oxide Flame Argon plasma Xenon…

A: AAS is a technique in which light energy of specific wavelength is absorbed by an atom/ion. This…

Q: Calculate the specific heat of a substance if 420 calories is needed to raise the temperature of…

A: Given, specific heat capacity of a substance (s) = ? Amount of heat needed (Q) = 420 cal Mass of a…

Q: Click the "draw structure" button to launch the drawing utility. Draw the structure of a molecule…

Q: 4. CH3CH₂CH₂NHCH₂CH₂CH3 CH, CH,CHNCH, T CH, -NH₂ o 5. 6.

Q: application of intergration

A: To determine the rate of a chemical reactions.

Q: Calculate the molarity of HCl in a solution, which was prepared by dissolving 5.5 g of HCl (molar…

A: Given, The mass of HCl = 5.5 g. The mass of C2H6O = 200 g. The density of the solution is 0.79…

Q: pH Table Substance pH A 11.3 B 2.3 C 9.4 D 7.4 E 3.0 Which has a pOH of 11.0? How many times more…

Q: The compounds below can undergo reduction to form a primary amine EXCEPT for what compound? A. NO₂…

Q: Propose a preparation reaction for the formation of CH3NHCH2CH3 from organic compounds with only 1…

Q: question 3: What is the name of the following protein using the three-letter codes? OH S 'N H₂N IZ Z…

Q: 1) NaOEt/EtOH/25°C 2) Br A H+/H₂O B OH/H₂O

A: Here we are required to draw the mechanism for the reaction .

Q: Copper can have improved wear resistance if alloyed with ceramic alumina, Al₂O3. If a copper alloy…

A: Given, Copper alloy has 7.8 % Al2O3

Q: Draw the product for the following reaction between an alkyne and one equivalent of HCI. HCI…

A: we need to draw the product of the reaction

Q: Sulfur dioxide and nitrogen dioxide react at 298 K via the reaction SO₂(g) + NO₂(g) = SO3(g) + NO(g)…

Q: 16.) Oxidative deamination occurs primarily on which of the following? a. mitochondria b. liver c.…

A: Since you have asked multiple question, we will solve the first question for you. If you want any…

Q: Fact: Zn-63 is unstable and radioactive. Is its n/p ratio too high or too low? Which process could…

A: Zn -63 is unstable and radioactive. On the basis of N/P ratio we will judge .

Q: What is the volume of 8.24 moles of Cl at STP? A. 184.576 B. 0.367 C. 22.4 O D. 185.756 * How many…

Q: Calculate the weight of a gas, with a density of 1.25 g/L that will fill a box of these dimensions:…

Q: Q.2) In the first order reaction of KI with K₂S₂O8 at 25 C, a 10 ml sample of the reaction required…

Q: 2. Balance the following redox reaction that takes place in an acidic solution using the…

A: In ion electron method first of all reaction is written in ionic form by removing spectator ions.…

Q: What product is formed when 234U undergoes 5 alpha emissions and 2 beta emissions in a total of…

A: During nuclear reaction sum of mass number and sum of atomic numbers is equal on reactant side and…

Q: Strong and weak acids differ greatly in their empirical and theoretical definitions. Identify…

Question

100%

In synthesizing primary (1°) amines by alkylation of NH3, explain how we can prevent the formation of 2°
and 3° amines as by-products? You can give an example to help you in explaining but it is not required. (please provide clear and complete explination

Definition Definition Organic compounds with a nitrogen atom having a lone pair of electrons on it. Amines are derived from ammonia (NH 3 ), wherein hydrogen atoms are substituted by an aryl or alkyl group.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

In synthesizing primary (1⁰) amines by alkylation of NH3, explain how we can prevent the formation of 2⁰ and 3⁰ amines as by-products? You can give an example to help you in explaining but it is not required.
Illustrate the cope elimination is an intramolecular E2 of tertiary amine oxides
Give only typing answer with explanation and conclusion What are the schemes for the following reactions?: Schemes: 1.Benzoic acid in NaOH 2.Acetic acid in NaHCO3 3.Propan-2-amine in water
Propose a reasonable Phase I and a Phase II metabolite for the following
Give a clear handwritten answer with explanation...how you will prepare a series of 1 ppm quinine sulphate solutions that contain 0.010, 0.020, 0.030, 0.040, or 0.050 M sodium bromide.
Explain why a much better yield of primary amine is obtained from the reaction of an alkyl halide with azide ion (-N3), followed by catalytic hydrogenation. (Hint: An alkyl azide is not nucleophilic.)
Answer the following questions on using IR spectroscopy to characterize the products in the synthesis ofluminol.a. Can IR be used to determine if the synthesis of the hydrazide was successful? Explain youranswer.b. IR cannot be used to determine the success of the reduction of the nitro group into an amine in Part II.Explain why not.
When cyclohexanol is dehydrated to cyclohexene, a gummy green substance forms onthe bottom of the flask. Suggest what this residue might be, and propose a mechanismfor its formation (as far as the dimer).
One of the heptanedione isomers below has a pka of approximately 9 rather than 20. Which isomer? Why? Draw its conjugate base and offer a full explanation of its acidity.
S.2. List the following compounds by discussing their basicity.
A student mixes benzaldehyde with an unknown symmetrical ketone, compound C, in an aqueous sodium hydroxide solution and produces compound D.Based on the 1H NMR of compound D, shown below, predict the structure of compound
In the preparation of p-Nitroaniline, there are three synthetic steps in this reaction, the first is acetylation of the amine, second is nitrates and the third is hydrolysis of the amide. Why must acetylation be done first if at all? Use chemical structures to illustrate your point.