In the following sequence, compound A is reacted with isopropyl alcohol which contains an isotopically labeled O atom (shown with the star). Draw the structures for compounds A, B and, C. Compound B will contain the isotopically labeled oxygen, so make sure to include the star beside the O isotope in that structure. Compound C may contain the labeled oxygen (or it may not), if you determine it does, you must make sure to label it. OH Scheme 1: Br SOCI₂ Scheme 2: pyridine A B Complete the following reaction schemes Mg A + LDA H reactive intermediate reactive intermediate B + Br NaOH → С A N H₂O H30 + C carboxylate anion
In the following sequence, compound A is reacted with isopropyl alcohol which contains an isotopically labeled O atom (shown with the star). Draw the structures for compounds A, B and, C. Compound B will contain the isotopically labeled oxygen, so make sure to include the star beside the O isotope in that structure. Compound C may contain the labeled oxygen (or it may not), if you determine it does, you must make sure to label it. OH Scheme 1: Br SOCI₂ Scheme 2: pyridine A B Complete the following reaction schemes Mg A + LDA H reactive intermediate reactive intermediate B + Br NaOH → С A N H₂O H30 + C carboxylate anion
Chapter5: Stereochemistry At Tetrahedral Centers
Section5.SE: Something Extra
Problem 41AP
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