Indicate the types of isomerisms exhibited by the complex [Co(NH3)5 (NO2)] (NO3)2. (At. no. Co = 27)

Q: Isomers for metal complexes are molecules with the same molecular formula and differ only in the…

A: The correct answer is given below

Q: INORGANIC CHEMISTRY II Differentiate the following complexes [PtCl4]2-, [PtCl3(PMe3)]-,…

A: The isomers which have a restricted rotation around the double bond is known as geometrical isomers.…

Q: (b) What are the effects of r-donor and t-acceptor ligands on the splitting of metal d orbitals in…

A: Answer- When the ligands approach the central metal ion, d- or f-subshell degeneracy is broken due…

Q: How do the relative magnitudes of Epairingand Δ affect theparamagnetism of a complex?

A:

Q: By using valence bond theory and ligand field theory, prove [Fe(acac)3] is a paramagnetic high spin…

A: The valence bond theory provides information about the structure and magnetic properties of the…

Q: The metal ion, M2+, formed a paramagnetic tetrahedral complex [MJ4]2+, having three unpaired…

A: Given: We have to calculate the hybridization of given M2+ ion.

Q: ) Figure 5 shows four energy diagrams, labelled A to D. The diagrams depict possible configurations…

A:

Q: Which dn configuration is not capable of giving low-spin and high-spin complexes in an octahedral…

A: According to the crystal field theory the ligand atom acts as point negative change and the metal…

Q: Explain the following: (i) Nickel does not form low spin octahedral complexes. (ii) The Tt-complexes…

A: Nickel does not form low spin octahedral complexes. Because, the electronic configuration of Nickel…

Q: The complex [CoFg]³¯ absorbs light at a wavelength of 290 nm. What is the value of the crystal filed…

A: Given: Wavelength = 290 nm Convert nm into m as follows.

Q: Why is the energy of the dxz and dyz orbitals in a square-planar complex lower than that of the dxy…

A: The "square planar geometry" contains 4 ligands attached with 1 "central metal atom". In this…

Q: What energy levels are occupied in a complex such ashexacarbonylchromium(0)? Are any electrons…

A: According to the molecular orbital theory, the atomic orbitals combine to form new molecular…

Q: Find a crystal structure for any metal complexes, define the oxidation state of metal, define the…

A:

Q: By using valence bond theory and ligand field theory, prove [Fe(acac)3] is a paramagnetic high spin…

A:

Q: Consider the coordination complex [Cr(OH2)3CI3]Br3 Identify the ligands by name (include the word…

A: Given complex--- [Cr(OH2)3Cl3]Br3

Q: 1.Show how a Fischer carbene complex can be prepared starting from Mo(CO)6 . 2.How would you explain…

A: Back donation:The carbonyl ligand that coordinated with the metal has electron rich sp orbital. The…

Q: Show how the coordination of two MeHNCH2CH2NH2 ligands to a metal atom in a square planar complex…

A: Optical isomers: Two compound having same molecular formula but different in spatial arrangement…

Q: Explain the following :(i) Low spin octahedral complexes of nickel are not known.(ii) The…

A: Low spin octahedral complexes are formed when the central metal atom undergo d2sp3 hybridisation by…

Q: octahedral complex is found to absorb visible light, with the absorption maximum occurring at 507…

A: The absorption with maximum wavelength by an electron is equal to the energy difference between…

Q: A four-coordinate complex MA2B2 is prepared and found tohave two different isomers. Is it possible…

A:

Q: 4. The structure of [Cu(NH3)4]²+ is known to be square planar. Using the ligand o orbitals only,…

A: Given that  Square planer metal complex [Cu(NH3)4]2+ (ML4) Draw orbitals symmetries of the central…

Q: The complex [COF6]¯ absorbs light at a wavelength of 290 nm. What is the value of the crystal filed…

A:

Q: 1. Draw the partial MO diagram for a [Fe(OH;)6J** using concepts from Ligand Field Theory. Fill in…

A: Hello. Since your question has multiple parts, we will solve the first question for you. If you want…

Q: The metal ion, M2+, formed a paramagnetic tetrahedral complex [MJ4]2+, having three unpaired…

A: The given metal ion is M2+

Q: Classify the stereoisomerism and structural isomerism of coordination compounds. Give three examples…

A: Answers are explained below. Stereoisomerism of coordination compound is as follows :

Q: Gmelin compound is an amine complex compound which was first isolated in solid form. The compound is…

A: Given options are : A. [Co(NH3)6](C2O4)2B. [Co(NH3)6(C2O4)3]C. [Co(NH3)6]2(C2O4)3D. [Co(NH3)6]C2O4…

Q: How does Ligand Field Theory explain the interaction between the ligand with the central metal…

A: Crystal Field theory explains bonding for transition metal complexes. The energy of crystal field…

Q: The values for lmax for complex A and B are 512 nm and 650 nm respectively.  A has the structure…

A: Given S.No. Complex  Imax 1 [Co(NH3)4CO3]NO3 512 nm 2 [Co(NH3)4Cl2]Cl.  650 nm Explain the…

Q: How many unpaired electrons are in the low-spin octahedral complex [Co(CN),Jª¯? Provide your answer…

A: The no. Of unpaired electron in given complex = 1 (one).

Q: 2. Sketch and name two geometrical isomers of [Cr(NH3)2(CO)4]2+ () Is this compound paramagnetic or…

A:

Q: Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit?

A: IUPAC name for [Cr(NH3)4Cl2]+ is tetraaminedichlorochromium (III)

Q: The factor determining the mechanism observed in the substitution reactions of square plane…

A: here, for the nucleophilic substitution reaction Sn2 for the inorganic reaction mechanism  yes, This…

Q: Most Zn2+complexes are colorless.

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Q: 2. Octahedral complex are shown as below. OCH3 H3CO LOCH3 Al H3CO rOCH3 OCH3 a. Calculate the CFSE…

A:

Q: What are the characters for the operations C2, C4, σd, and σv(xz) respectively, on the LCAO Ψ(L1+L3)…

A: Cn is a rotation of (360/n)". C2= 180°rotation, C4= 90°rotation

Q: The values for lmax for complex A and B are 512 nm and 650 nm respectively.  A has the structure…

A: 1)

Q: [FeF6]° , [Fe(CN)«]+

A: If the complex have unfilled orbitals, i.e., unpaired electrons, it is called a paramagnetic…

Q: 1. The UV-visible spectrum of an aqueous solution of CuSO, (which contains a Cu2+ metal center)…

A: ∆Oct is an energy term, representing the energy gap between the splitted orbitals and have an…

Q: When MCl4(NH3)2 is dissolved in water and treated withAgNO3, 2 mol of AgCl precipitates immediately…

A: When MCl4(NH3)2 is dissolved in water and treated withAgNO3, 2 mol of AgCl precipitates immediately…

Q: Does the square-planar complex ion [Pt(NH3)(N3)ClBr]- haveoptical isomers? Explain your answer.

A: The isomers which have same atoms and bonds but different spatial arrangements are known as optical…

Q: The complex [FeL2X2] {where L = 1,10-phenanthroline and X = thiocyanate} gives a magnetic moment,…

A: The answer of the question is given below:

Q: [Mn(H2O)6]?* complex has an extremely pale color, attributable to transitions which are formally…

A:

Q: The complex diamminedichloronickel(II), (Ni(NH3)2C12], is paramagnetic and does not have any…

A: When a metal linked with the ligands then it is known as coordination compound.

Q: A complex of the type [M(AA)2X2]n+ is optically active,giving a suitable example. comment on the…

A: If the substances  which is under observation are non-superimposable mirror images of each other and…

Q: When Werner's student Edith Humphrey first synthesized the complex complex salts of formula…

A: This is an example of Linkage isomerism of -NO2 ligand.  When a particular ligand is binding to a…

Q: What type of isomerism is shown by each of the following complexes: (i) [Pt(NH3)2Cl2] (ii)…

A: Isomers are molecules or polyatomic ions with identical molecular formulas that is, same number of…

Q: Write the formula for a complex formed between Ag+ and NH, with a coordination number of 2. formula:…

A:

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.