Instant hot packs contain a solid and a pouch of water. When the pack is squeezed, the pouch breaks and the solid dissolves, increasing the temperature because of the exothermic reaction. The following reaction is used to make a hot pack: LiCl(s)⟶Li+(aq)+Cl−(aq) ΔH=−36.9kJ What is the final temperature in a squeezed hot pack that contains 27.3 g of LiCldissolved in 105 mL of water? Assume a specific heat of 4.18 J/(g⋅∘C) for the solution, an initial temperature of 25.0 ∘C, and no heat transfer between the hot pack and the environment.
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
Instant hot packs contain a solid and a pouch of water. When the pack is squeezed, the pouch breaks and the solid dissolves, increasing the temperature because of the exothermic reaction.
The following reaction is used to make a hot pack:
LiCl(s)⟶Li+(aq)+Cl−(aq) ΔH=−36.9kJ
What is the final temperature in a squeezed hot pack that contains 27.3 g of LiCldissolved in 105 mL of water? Assume a specific heat of 4.18 J/(g⋅∘C) for the solution, an initial temperature of 25.0 ∘C, and no heat transfer between the hot pack and the environment.
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