The above reaction was studied (at a particular temperature) and the following data (for rate = -d[ClO2]/dt) were obtained:     [ClO2]0   [OH-]0   Initial Rate (mol/L)   (mol/L)   (mol L-1 s-1) 0.170      0.170      1.43 0.340      0.085      2.87 0.340      0.170      5.74 hello, i am confused about the order of clo2 given the data above. When 1 use rate 1 and 2 given thier respective clo2 intial concentrations, i get first order for clo2, but when i use rate 1 and rate 3 and thier respective clo2 intial concentrations, i get an order of 2 for clo2. so which order is correct for clo2 given this data? first order or second order?

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter12: Chemical Kinetics
Section: Chapter Questions
Problem 110CP: Consider a reaction of the type aA products, in which the rate law is found to he rate = k[A]3...
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2ClO2(aq) + 2OH-(aq)  ClO3-(aq) + ClO2-(aq) + H2O(l)

 

The above reaction was studied (at a particular temperature) and the following data (for rate = -d[ClO2]/dt) were obtained:

 

 

[ClO2]0   [OH-]0   Initial Rate
(mol/L)   (mol/L)   (mol L-1 s-1)
0.170      0.170      1.43
0.340      0.085      2.87
0.340      0.170      5.74

hello, i am confused about the order of clo2 given the data above. When 1 use rate 1 and 2 given thier respective clo2 intial concentrations, i get first order for clo2, but when i use rate 1 and rate 3 and thier respective clo2 intial concentrations, i get an order of 2 for clo2. so which order is correct for clo2 given this data? first order or second order?

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