Kinetic data were obtained on the aqueous reaction of hydrogen peroxide with iodide ion and H+. H2O2(aq) + 3 l-(aq) + 2 H+(aq) → 13-(aq) + 2 H2O(1) Exp. 1 [H₂O₂], M 0.010 [1], M [H-], M 0.00050 Initial Rate, M/s 1.15 x 10-6 0.010 2 0.020 0.010 0.00050 4.60 x 10-6 3 0.010 0.020 0.00050 1.15 x 10-6 4 0.010 0.010 0.00100 2.30 x 10-6 Determine the rate law for the reaction: none of the answers are correct R = 2.3 M-2 S-1 [H2O2]2 [H+] R = 1.15 x 10-2 M-1 S-1 [H2O2]2 R = 0.0115 M-1 S-1 [H2O2] [-]

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.3: Rate Law And Order Of Reactions
Problem 11.5PSP
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Kinetic data were obtained on the aqueous reaction of hydrogen peroxide with
iodide ion and H+. H2O2(aq) + 3 l-(aq) + 2 H+(aq) → 13-(aq) + 2 H2O(1)
Exp.
1
[H₂0₂], M
0.010
[I], M
0.010
[H+], M
0.00050
Initial Rate, M/s
1.15 x 10-6
2
0.020
0.010
0.00050
4.60 x 10-6
3
0.010
0.020
0.00050
1.15 x 10-6
4
0.010
0.010
0.00100
2.30 x 10-6
Determine the rate law for the reaction:
none of the answers are correct
R = 2.3 M-2 S-1 [H2O2]2 [H+]
R = 1.15 x 10-2 M-1 S-1 [H2O2]2
R = 0.0115 M-1 S-1 [H2O2] [-]
Transcribed Image Text:Kinetic data were obtained on the aqueous reaction of hydrogen peroxide with iodide ion and H+. H2O2(aq) + 3 l-(aq) + 2 H+(aq) → 13-(aq) + 2 H2O(1) Exp. 1 [H₂0₂], M 0.010 [I], M 0.010 [H+], M 0.00050 Initial Rate, M/s 1.15 x 10-6 2 0.020 0.010 0.00050 4.60 x 10-6 3 0.010 0.020 0.00050 1.15 x 10-6 4 0.010 0.010 0.00100 2.30 x 10-6 Determine the rate law for the reaction: none of the answers are correct R = 2.3 M-2 S-1 [H2O2]2 [H+] R = 1.15 x 10-2 M-1 S-1 [H2O2]2 R = 0.0115 M-1 S-1 [H2O2] [-]
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