(m) DMP, CH2CI2 PCC, CH2CI2 Pyridinium chlorochromate in methylene chloride solvent Aco OAc -OAc OH 1. DMSO, (COCI)2 2. Et3N Dimethylsulfoxide & oxalyl chloride followed by triethylamine OAc = Dess-Martin Periodinane (DMP) in methylene chloride solvent

(m) DMP, CH2CI2 PCC, CH2CI2 Pyridinium chlorochromate in methylene chloride solvent Aco OAc -OAc OH 1. DMSO, (COCI)2 2. Et3N Dimethylsulfoxide & oxalyl chloride followed by triethylamine OAc = Dess-Martin Periodinane (DMP) in methylene chloride solvent

Appl Of Ms Excel In Analytical Chemistry

2nd Edition

ISBN:9781285686691

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Chapter12: Spectrochemical Methods

Section: Chapter Questions

Problem 13P

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Question

Draw the product of the reaction.

(m) DMP, CH2CI2
PCC, CH2CI2
Pyridinium chlorochromate in
methylene chloride solvent
Aco OAc
-OAc
OH
1. DMSO, (COCI)2
2. Et3N
Dimethylsulfoxide & oxalyl
chloride followed by
triethylamine
OAc =
Dess-Martin Periodinane
(DMP)
in methylene chloride
solvent

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