Below, depicts the electron flow process for the synthetic schemes. This should include the prediction of significant and by-products through electronic and structural impacts. The mechanism for pushing the arrow must be shown. SYNTHESIS OF TEREPHTALIC ACID AICI3 HCI CH3CI toluene Scheme 1. F'orun of Telvere ume i'nerket Crat Allsluren Br2 FeBr3 Br toluene o-Bromotoluene p-Bromotoluene Scheme 2. Bromination uf Toluene using BryFeBra Mg C=0 ether Mg phenylmagnesium bromide Br p-Bromotoluene acetic acid Scheme 3. Bromo 1 methyl berzene forms Grignard reagent upon reacting magnesium KMN04 но он HO, acetic acid Terephthalic acid Scheme 4. Bronw i wetle becoie eeed dergo axicdetion in presence of perasston permongate to form COXOH and we get the desired acad (Tereplithali: acidy

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter15: Radical Reactions
Section: Chapter Questions
Problem 11E
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Below, depicts the electron flow process for the synthetic schemes. This should include the
prediction of significant and by-products through electronic and structural impacts. The mechanism
for pushing the arrow must be shown.
SYNTHESIS OF TEREPHTALIC ACID
AICI3
CH3CI
+ HCI
toluene
Scheme 1. Formm of Yeluere wme 'rerke: Cra Alistaren
Br2
FeBr3
Br
toluene
o-Bromotoluene
p-Bromotoluene
Scheme 2. Bronination of Toluene using Bry/FeBr
Mg
C=C
Br
MoBr
ether
p-Bromotoluene
phenylmagnesium bromide
acetic acid
Scheme 3. Bromo I methyl bencene forms Grignard reagent upon reacting
magnesium
KMN04
HO
OH
acetic acid
Terephthalic acid
Scheme 4. Bronno i metlyl benzoie ccid undergo axicetion in presence of poassim
permangravate to form CXOH and we get the desired acad (Tereplthale ocid)
Transcribed Image Text:Below, depicts the electron flow process for the synthetic schemes. This should include the prediction of significant and by-products through electronic and structural impacts. The mechanism for pushing the arrow must be shown. SYNTHESIS OF TEREPHTALIC ACID AICI3 CH3CI + HCI toluene Scheme 1. Formm of Yeluere wme 'rerke: Cra Alistaren Br2 FeBr3 Br toluene o-Bromotoluene p-Bromotoluene Scheme 2. Bronination of Toluene using Bry/FeBr Mg C=C Br MoBr ether p-Bromotoluene phenylmagnesium bromide acetic acid Scheme 3. Bromo I methyl bencene forms Grignard reagent upon reacting magnesium KMN04 HO OH acetic acid Terephthalic acid Scheme 4. Bronno i metlyl benzoie ccid undergo axicetion in presence of poassim permangravate to form CXOH and we get the desired acad (Tereplthale ocid)
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