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MC1. Grignard reagent and organolithium reagents can be prepared in presence of acidic functional groups. MC2. Gilman reagents react with formaldehyde and gives alcohol. MC3. An S№2 attack on the chiral center would result in inversion of stereochemistry.

MC1. Grignard reagent and organolithium reagents can be prepared in presence of acidic functional groups. MC2. Gilman reagents react with formaldehyde and gives alcohol. MC3. An S№2 attack on the chiral center would result in inversion of stereochemistry.

Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter24: Carboxylic Acids & Derivatives
Section: Chapter Questions
Problem 26E
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MC1. Grignard reagent and organolithium reagents can be prepared in presence of acidic functional groups. MC2. Gilman reagents react with formaldehyde and gives alcohol. MC3. An SN2 attack on the chiral center would result in inversion of stereochemistry. MC4. Acetal cannot be formed in base as the -OH group is a bad leaving group. MC5. Carbon dioxide can readily react with Gilman reagent to form carboxylic acid. MC6. Alkynes anion are powerful nucleophiles that react with epoxides, aldehyde and ketones. MC7. Simple phosphonium yilde forms the Z product which is the thermodynamic product. MC8. When the reaction is under kinetic control the ratio of the products formed is determined by the relative energies of the transition states. MC9. A significant concentration of strong acids and strong bases cannot co-exist in the same reaction. MC10. The driving force for the Wittig reaction is the formation of a strong carbon-carbon double bond. MC11. A baby-shark trap can be used to remove alcohol or water from the reaction mixture. MC12. Phosphonium ylide can be formed from a 3º Haloalkane. MC13. Consider the following reversible dehydration reaction. Adding water to the reaction would form the alkene. OH Cat H₂SO4 OCH3 H₂O MC14. Consider the following reversible Hydrolysis of Ester reaction. Adding water to the reaction would form the ester. H₂O Cat H₂SO4 OH CH3OH
Transcribed Image Text:MC1. Grignard reagent and organolithium reagents can be prepared in presence of acidic functional groups. MC2. Gilman reagents react with formaldehyde and gives alcohol. MC3. An SN2 attack on the chiral center would result in inversion of stereochemistry. MC4. Acetal cannot be formed in base as the -OH group is a bad leaving group. MC5. Carbon dioxide can readily react with Gilman reagent to form carboxylic acid. MC6. Alkynes anion are powerful nucleophiles that react with epoxides, aldehyde and ketones. MC7. Simple phosphonium yilde forms the Z product which is the thermodynamic product. MC8. When the reaction is under kinetic control the ratio of the products formed is determined by the relative energies of the transition states. MC9. A significant concentration of strong acids and strong bases cannot co-exist in the same reaction. MC10. The driving force for the Wittig reaction is the formation of a strong carbon-carbon double bond. MC11. A baby-shark trap can be used to remove alcohol or water from the reaction mixture. MC12. Phosphonium ylide can be formed from a 3º Haloalkane. MC13. Consider the following reversible dehydration reaction. Adding water to the reaction would form the alkene. OH Cat H₂SO4 OCH3 H₂O MC14. Consider the following reversible Hydrolysis of Ester reaction. Adding water to the reaction would form the ester. H₂O Cat H₂SO4 OH CH3OH
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