Metal alkylidenes are an important class of organometallic chemistry where metal is doub bonded with carbenes ([M]=CR2). Answer the following question for metal alkylidenes: (a) show orbital diagram to explain the bonding in metal alkylidenes, (b) how the other substituents on metal would affect its stability, and (c) discuss their role in (i) olefin metathesis, (ii) ring-opening metathesis, and (iii)

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter29: Organic Polymer Chemistry
Section: Chapter Questions
Problem 29.9P
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Metal alkylidenes are an important class of organometallic chemistry where metal is double
bonded with carbenes ([M]=CR2). Answer the following question for metal alkylidenes:
(a)
show orbital diagram to explain the bonding in metal alkylidenes,
(b)
how the other substituents on metal would affect its stability, and
(c)
discuss their role in (i) olefin metathesis, (ii) ring-opening metathesis, and (iii)
ring-closing metathesis with specific examples and catalytic cycles.
Transcribed Image Text:Metal alkylidenes are an important class of organometallic chemistry where metal is double bonded with carbenes ([M]=CR2). Answer the following question for metal alkylidenes: (a) show orbital diagram to explain the bonding in metal alkylidenes, (b) how the other substituents on metal would affect its stability, and (c) discuss their role in (i) olefin metathesis, (ii) ring-opening metathesis, and (iii) ring-closing metathesis with specific examples and catalytic cycles.
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