Methane and hydrogen sulfide react to form carbon disulfide and hydrogen, like this: CH, (g)+2H,S(g) Cs, (g)+4H, (g) Suppose a mixture of CH4, H,S, CS, and H, has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. dlo perturbation change in composition shift in equilibrium O to the right The pressure of CH, will O to the left Some H, is removed. The pressure of H,S will O (none) O to the right Some H,S is added. The pressure of CH, will O to the left The pressure of CS, will O (none) go up. go down. not change.

Chemistry: The Molecular Science
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Chapter16: Thermodynamics: Directionality Of Chemical Reactions
Section: Chapter Questions
Problem 105QRT
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Methane and hydrogen sulfide react to form carbon disulfide and hydrogen, like this:
CH,(g)+2H,S(g)
→ Cs,(e)+4H, (g)
Suppose a mixture of CH,, H,S, CS, and H, has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table
below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left.
olo
perturbation
change in composition
shift in equilibrium
Ar
to the right
The pressure of CH4 will
to the left
Some H, is removed.
The pressure of H,S will
O (none)
to the right
The pressure of CH4 will
to the left
Some H,S is added.
The pressure of CS, will
v ?
(none)
go up.
go down.
not change.
Transcribed Image Text:Methane and hydrogen sulfide react to form carbon disulfide and hydrogen, like this: CH,(g)+2H,S(g) → Cs,(e)+4H, (g) Suppose a mixture of CH,, H,S, CS, and H, has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. olo perturbation change in composition shift in equilibrium Ar to the right The pressure of CH4 will to the left Some H, is removed. The pressure of H,S will O (none) to the right The pressure of CH4 will to the left Some H,S is added. The pressure of CS, will v ? (none) go up. go down. not change.
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