Mixture #2 Mixture #3 Mixture #4 Mixture #5 Average

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter26: Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 26.21QAP
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Can you help me find the mixtures and the average on the second page. The first page has the experimental data on it

Conclusion:
K
Mixture #1
133
Mixture #2
Mixture #3
Mixture #4
Mixture #5
Average
|
|||
Transcribed Image Text:Conclusion: K Mixture #1 133 Mixture #2 Mixture #3 Mixture #4 Mixture #5 Average | |||
Vol. of 2.00 x 10³ M
Vol. of 2.00 x 10:3 M
Vol. of H20
Mixture
Fe(NO;)3 (in mL)
KSCN (in mL)
(in mL)
Absorbance
[FESCN*2] = A/5x103
1
5.00
1.00
4.00
.115
.115/5x103 = 2.3x10-5M
5.00
2.00
3.00
.234
.340
3
5.00
3.00
2.00
4
5.00
4.00
1.00
.430
.525
5.00
5.00
0.00
Mixture 1 Calculation:
Fe*3
SCN-1
FESCN+2
Start (2x10-³M)(5ml) = 1x10-3M
(10ml)
-X
(2x10-3M)(1ml) = 2×104M
((10ml)
-X
Change
X+
Equil. 1x10-3М-X
2×104M -X
9.77х104M
1.77x10-M
2.3x10-5M
K = [FESCN+21
[Fe**][ SCN]
= 133
Transcribed Image Text:Vol. of 2.00 x 10³ M Vol. of 2.00 x 10:3 M Vol. of H20 Mixture Fe(NO;)3 (in mL) KSCN (in mL) (in mL) Absorbance [FESCN*2] = A/5x103 1 5.00 1.00 4.00 .115 .115/5x103 = 2.3x10-5M 5.00 2.00 3.00 .234 .340 3 5.00 3.00 2.00 4 5.00 4.00 1.00 .430 .525 5.00 5.00 0.00 Mixture 1 Calculation: Fe*3 SCN-1 FESCN+2 Start (2x10-³M)(5ml) = 1x10-3M (10ml) -X (2x10-3M)(1ml) = 2×104M ((10ml) -X Change X+ Equil. 1x10-3М-X 2×104M -X 9.77х104M 1.77x10-M 2.3x10-5M K = [FESCN+21 [Fe**][ SCN] = 133
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