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Answer Q34, 35, 36
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- Represent a diastereoisomer of theproposed molecule, indicate theabsolute settings of your carbonschirals and discuss whether this is optically activeor not - justify:Give atleast three characteristics of dichloromethane that make it a good extracting solvent for alkaloid.Give only typing answer with explanation and conclusion Which of the following statements is/are incorrect? (6,25 p) I- In order for an organic compound to be a dyestuff, it must be chromor and auxochrochrome. II- Hydroxyl or amino groups can be given as examples of chromophore groups III- Decrease of chromophore groups in a molecule causes color deepening. A. b) II, III B. a) I only C. d) II only D. c) III only
- The global consumption of synthetic dyes is increasing due to increase in demand invarious processing/manufacturing industries. Analyze why among the large number of organic molecules, only relatively few moleculesare considered as dyes. Select any one dye which is used in industry and give justificationof type of the dye, its application in the industry and related reactions.Describe with a suitable example why the characterisation of chiral compounds is important to the pharmaceutical industry and indicate why separation of the enantiomers can prove challenging. Explain how capillary electophoresis can be used in the analysis of these compounds.) PLA, a polyester-based synthetic polymer, decomposes in our body fluid and separates into its constituent acids and alcohol. This acid in the body can cause inflammation. What would you recommend to overcome this disadvantage? b) The late decomposition of PLA, which is a biodegradable and hydrophobic polymer, in body fluid may create a disadvantage in applications where faster degradation is desired. What would you suggest to do to resolve this situation? Please explain.
- Define Polylactic acid dissolvining in chloroform?Starting with benzene, give a sequence of laboratory reactions which could be used to prepare p-isopropylaniline. If separation of ortho, meta, or para-isomers is required, give evidence that it is feasible.Give and observation and inference when the compound hexane is subjected into test for Br2 in CCl4
- The IR and NMR spectra of the material whose structure formula is C16H22O4 are given below.To this datawhat could be the ingredient?The UV–visible spectrum of GLB-1 is given in Figure 2. i.What colour(s) will the deoxy and oxy forms of GLB-1 be? Note, an electromagnetic spectrum is reproduced in the Assessment area on the S315 website. ii.By comparing the bands on the right-hand side (around 550 nm) with those of oxy- and deoxymyoglobin, suggest what type of transition gives rise to these bands.The following is an experimental account of the preparation of compound B from Phenylamine. 2cm3 of phenylamine are dissolved in 10cm3 of 0.5M hydrochloric acid in a test tube and cooled in an ice bath. 5cm3 of 0.2M sodium nitrate solution cooled to about 5o are added to the solution above and shaken. A salt A, C6H5N2Cl is formed, collected and dried. 1g of salt A is dissolved in 10cm3 of water, cooled and added drop by drop to a cold solution of 0.3g phenol in 5cm3 of 0.1M sodium hydroxide solution. B is precipitated, filtered, dried and the melting point determined. B is further crystallized twice and the melting point taken each time and found to be constant. Questions: (i) Give the name and suggest the colour of the precipitate B. Hence explain why it is necessary to recrystallize B several times. (ii) Why was it necessary to obtain a constant melting point for B?