Name, draw and describe the organic product of the reaction between 2-methylbut-1-ene and H2O in the presence of H2SO4 and provide a clear rationale as to why this is the major product of the reaction.
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Name, draw and describe the organic product of the reaction between 2-methylbut-1-ene and H2O in the presence of H2SO4 and provide a clear rationale as to why this is the major product of the reaction.
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- Name, draw and describe the organic product of the reaction between 2-methylbut-1-ene and H2O in the presence of H2SO4 and provide a clear rationale as to why this is the major product of the reaction and the minor product of the reaction.(i) Name, draw and describe the organic product of the reaction between 2-methylbut-1-ene and H2O in the presence of H2SO4 and provide a clear rationale as to why this is the major product of the reaction. (ii) The elimination reaction between 2-bromobutane and NaOCH2CH3 gives two organic products. Draw a mechanism for the reaction which produces the major organic elimination product and provide a rationale as to why that is the major product.(1) Name the major product of the reaction between (S)-2-bromohexane and KCH3COO. Be specific with the configuration. (2) Name the alcohol that will produce the most stable intermediate and the dehydration product 2-methyl-1,3-pentadiene. (3) Give the name of the product between benzyl alcohol and pyridinium chlorochromate.
- The careful choice of an appropriate solvent will play a major role in whether organic reactions will be successful. For example, reagents such as CH3CH2Li and NaNH2 will be incompatible with solvents such as water and ethanol. Why is this?3-Chloro-2-methylpropene reacts with sodium methoxide in methanol to form 3-methoxy-2-methylpropene. For each of the following changes in the reaction conditions, state whether the reaction rate would increase, decrease, or remain the same. Explain your reasoning. In some cases the identity of the major organic product would be expected to change; in such cases, give the expected major product. (a) the same quantities of reagents are dissolved in half the volume of methanol (b) 3-bromo-2-methylpropene is used in place of 3-chloro-2-methylpropene (c) sodium methanethiolate (CH3SNa) is used in place of of sodium methoxide3-Chloro-2-methylpropene reacts with sodium methoxide in methanol to form 3-methoxy-2-methylpropene. For each of the following changes in the reaction conditions, state whether the reaction rate would increase, decrease, or remain the same. Explain your reasoning. In some cases the identity of the major organic product would be expected to change; in such cases, give the expected major product. (a) dimethyl sulfoxide (DMSO) is used in place of methanol (b) methanol is used by itself without sodium methoxide (c) 1-chloro-2,2,-dimethylpropane is used in place of 3-chloro-2-methylpropene
- 6. Write the structure of the organic product in each of the following reactions. Assume only monosubstitution for electrophilic aromatic substitution reactions. B HNO, acetic acid OH بلی NO₂ CI NO₂ Br₂ CHC NHANH, "OH CHÍNH, H₂SOWhy does the reaction of t-butanol with sulfuric acid gives the elimination product isobutylene whereas the reaction with HCl gives predominantly the substitution product?The reaction of DBU with 2-bromoheptane gives two alkene products, what are they? Which of these would you expect to be the major product? Explain your answer.
- Write a series of reactions leading to para-bromoethylbenzene, beginning with benzene and using other reagents as needed. What isomeric side products might also be formed?Write structural formulas for all the alkenes that can be formed in the reaction of 2-bromobutane with potassium ethoxide (KOCH2CH3).Photochemical chlorination of 2,2,4-trimethylpentane gives four isomeric monochlorides. (a) Write structural formulas for these four isomers. (b) The two primary chlorides make up 65% of the monochloride fraction. Assuming that all the primary hydrogens in 2,2,4-trimethylpentane are equally reactive, estimate the percentage of each of the two primary chlorides in the product mixture.
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