Name the following:   a) Na3[FeBr6]                                          b) [Cr(CN)2(H2O)]2+                                 c) [CoCl2(NH3)(en)2]Cl

Q: Rhol(PPhs)s 9volume eICCtronsinRn in Cr which are The L-type ligands? Oxidanon State of Rn,cr…

A: The L type ligands in [RhCl(PPh3)3] is PPh3; i.e. triphenylphosphine. The L type ligand in Cr(CO)6…

Q: INORGANIC CHEMISTRY II Differentiate the following complexes [PtCl4]2-, [PtCl3(PMe3)]-,…

A: The isomers which have a restricted rotation around the double bond is known as geometrical isomers.…

Q: chelating ligands?

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Q: Which model(s) accounts for the magnetism and color of coordination compounds? I. Lewis model II.…

A: Lewis model is a way of representing the atoms and electrons that constitute the bond. Localised…

Q: Which ligand below gives the LEAST stability to Pd2+ in forming a square planar complex? О а. NH3 O…

A: a) NH3 will form the least stable complex.  Because we know that more is the basicity of lignad more…

Q: By using valence bond theory and ligand field theory, prove [Fe(acac)3] is a paramagnetic high spin…

A: The valence bond theory provides information about the structure and magnetic properties of the…

Q: ) Figure 5 shows four energy diagrams, labelled A to D. The diagrams depict possible configurations…

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Q: C.Draw the molecular orbital diagram for B2 and find the bond order? D.The geometry of [Ni(CN)4]2-…

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Q: By using valence bond theory and ligand field theory, prove [Fe(acac)3] is a paramagnetic high spin…

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Q: A complex, ML62+, is violet. The same metal forms a complex with another ligand, Q, that creates a…

A: Given: The complex given is  This complex is violet. The metal gets attached to the weak field…

Q: Is this complex K3[Fe(C2O4)3].3H2O paramagnetic or diamagnetic, explain?

A: We will discuss whether this  complex K3[Fe(C2O4)3].3H2O  is paramagnetic or diamagnetic.

Q: octahedral complex is found to absorb visible light, with the absorption maximum occurring at 507…

A: The absorption with maximum wavelength by an electron is equal to the energy difference between…

Q: A spectrochemical series is a series of chemical units that contribute to ligand field splitting…

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Q: (a) Predict whether the glycinate ion, H2N-CH COO is a monodentate, bidentate, or tridentate ligand:…

A: a. Bidentate ligands are Lewis bases that donate two pairs of electrons to a metal atom.   It is a…

Q: a. Classify the isomer below and give the name of the isomers. [Cr(CO)6][CoCl6] and [Co(CO6)][CrCl6]…

A: The detailed solution of your question given below-- Since, we know that the concept of isomers in…

Q: Take the following complexes into account: A)[Co(en);]I3 B) Liq[COF3(OH)3] a) Which type of…

A: Hello. Since your question has multiple sub-parts, we will solve the first three sub-parts for you.…

Q: By taking into account the following complexes: A) [Co(en):]³* B)[CoCl3Br3]+ a) Give the oxidation…

A: In this question, we have to find out the correct answer of given problem by the help of the…

Q: 1. Draw the partial MO diagram for a [Fe(OH;)6J** using concepts from Ligand Field Theory. Fill in…

A: Hello. Since your question has multiple parts, we will solve the first question for you. If you want…

Q: True or false: a. Weak field ligands tend to form low spin complexes upon binding with metal…

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Q: W, X, Y, and Z are different monodentate ligands.a. Is the square planar [NiWXYZ]2+ optically…

A: a)

Q: a) Trialkylphosphine and ammonia are both strong-field ligands. However, experimental data show that…

A: Solution for a, PR3 ligands cause higher Δo than the NH3 because PR3 is σ-donor as well as…

Q: Assign oxidation states to the transition-metal ions in the following compounds: TiO2, ZrCl4, VCl3,…

A: Oxidation state indicates the degree of oxidation for an atom in a chemical compound; it is the…

Q: 2. Rank the ligands in order of their increasing effect on Act for Cr³+. Do this by looking at the…

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Q: Draw molecular orbital diagram, write complete electronic configuration and calculate bond order for…

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Q: When the valence d orbitals of the central metal ion are split in energy in an octahedral ligand…

A: Question.1:-  When the valance d-orbital of central atom split in energy in an octahedral ligand…

Q: 3+ cation, the energies of the valence d orbitals on When a certain strong-field ligand forms an…

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Q: Name the following ligands: A.H2NCH2.CH2NH2 B. NO3 C. NH3 D. Br

A: a) Ethylenediamine b) Nitrato

Q: With your knowledge in coordination chemistry, help these students label the solutions.

A: In contrast to non-transition metal ions, transition metal complex ions are usually colored because…

Q: Sketch the structures of the following complexes. Indicate any cis, trans, and optical isomers.(a)…

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Q: Explain the following: (i) Low spin octahedral complexes of nickel are not known. (ii) The…

A: Low spin octahedral complexes are formed when the central metal atom undergo d2sp3 hybridisation by…

Q: Depict and explain the Crystal field stabilization theory based on the color the below complexes.…

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Q: For the hexacyanoferrate(III) ion, [Fe(CN)6]^3- calculate the crystal field stabilization energy…

A: Given : We have to calculate the CFSE for [Fe(CN)6]3- .

Q: Consider the transition metal M which, in neutral form, has an electronic configuration ending in…

A: Oxidation state is defined as charge on central transition metal ion.

Q: Using IUPAC norms write the formulae for the following coordination compounds: (i)…

A: i) Metal name ends with -ate. That means, the complex is anionic. In the given coordination compound…

Q: Consider the coordination compound [Ni(C₂O4)2(H₂O)2] Cl2 and identify ligands a. C₂04-2, CI- -2 O b.…

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Q: Considering that [Cr (OH2) 6] Cl3 compound is purple, [Cr (NH3) 6] Cl3 compound is yellow, which of…

A: The compound [Cr(H2O)6 ]Cl3 is purple, and [Cr(NH3)]Cl3 compound is yellow in colour. Both complexes…

Q: Draw orbital-energy splitting diagrams and use the spec-trochemical series to show the orbital…

A: The ligands have an unshared electron and they function as a Lewis base. When the unshared electron…

Q: 1. Sketch all isomers of the following. Indicate clearly each pair of enantiomers. Multidentate…

A: 1. a) [Cr(bipy)(H2O)BrF]+: It is a coordination compound with four types of ligands attached to the…

Q: ) trans-[Co(en)2Cl2]Cl is a chiral compound ) The coordination number for the anionic complex in…

A: If any molecule has sigma plane of symmetry or inversion centre , then we can say the molecule is…

Q: Give the systematic name of this coordination compound. [(en), ]Cl, systematic name:

A: Rules for naming complex compounds :-  In coordination sphere ligands are named fist in alphabetical…

Q: 3- The gap between the higher and lower energy levels is called the crystal-field splitting energy…

A: Strong field ligands cause a greater splitting of the d-orbitals of the central metal atom, than the…

Q: Which of the metal complexes below is expected to be stable? Be specific in your explanation! a.…

A: - complex is more stable, than

Q: Write the Werner's formula of a coordination compound called Sodium diaquatetrachlorocobaltate(Il).

A: Werner's theory tells us that metal have two valencies. They are primary and secondary valency. The…

Q: а. РМе3 b. NH3 с. en

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Q: (a) Construct a clearly labelled molecular orbital energy level diagram for an octahedral complex…

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Q: b) Calculate the orbital multiplicity for a Cr3+ assuming it is a free ion (Not complex). c)…

A: Orbital multiplicity of a metal is its total no.of orientations of orbital angular momentum L. which…

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.