A spectrochemical series is a series of chemical units that contribute to ligand field splitting arranged in order of their strength. Use the following spectrochemical series to answer the questions below: I < Br¯ < S²¯ < SCN¯ < Cl¯

Principles of Instrumental Analysis
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Chapter14: Applications Of Ultraviolet-visible Molecular Absorption Spectrometry
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A spectrochemical series is a series of chemical units that contribute to ligand
field splitting arranged in order of their strength. Use the following
spectrochemical series to answer the questions below:
3.
IT < Br < S2¯ < SCN¯ < Cl¯ <F¯ < H20 < NH3 < PPH3 <
CN CO
Show the splitting and label the d-orbitals for each complex described below.
Add in the appropriate number of electrons. Choose from these labels for each
complex:
eg (bonding), Eg*, t2g (non-bonding), t2g (bonding), and t2g*,
EXAMPLE: [Mn(H2O)6]²*
++ :
+++ t2e (non-bonding)
i) [CoBr6]4=
ii) [Ni(NH3)6]2+
iii) MnCl2(H2O)4 (pretend the symmetry is On)
iv) [Fe(CN)6]³-
Energy
Transcribed Image Text:A spectrochemical series is a series of chemical units that contribute to ligand field splitting arranged in order of their strength. Use the following spectrochemical series to answer the questions below: 3. IT < Br < S2¯ < SCN¯ < Cl¯ <F¯ < H20 < NH3 < PPH3 < CN CO Show the splitting and label the d-orbitals for each complex described below. Add in the appropriate number of electrons. Choose from these labels for each complex: eg (bonding), Eg*, t2g (non-bonding), t2g (bonding), and t2g*, EXAMPLE: [Mn(H2O)6]²* ++ : +++ t2e (non-bonding) i) [CoBr6]4= ii) [Ni(NH3)6]2+ iii) MnCl2(H2O)4 (pretend the symmetry is On) iv) [Fe(CN)6]³- Energy
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