2.4. Draw the structures of the product(s) described for each reaction. Specify allaspects of the stereochemistry.a. stereospecific anti addition of bromine to cis- and trans-cinnamic acid.b. methanolysis of S-3-bromooctane with 6% racemization.c. stereospecific syn thermal elimination of acetic acid from 1R,2S-diphenylpropyl acetated. stereoselective epoxidation of bicyclo[2.2.1]hept-2-ene proceeding 94% fromthe exo face.

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Answered: 2.4. Draw the structures of the…

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2.4. Draw the structures of the product(s) described for each reaction. Specify all aspects of the stereochemistry.

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter8: Addition Via Carbocation

Section: Chapter Questions

Problem 6CTQ

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Concept explainers

Amines

Amines are organic compounds with a nitrogen atom having a lone pair of electrons on it. They are derived from ammonia (NH3) wherein hydrogen atoms are substituted by an aryl or alkyl group.

Question

2.4. Draw the structures of the product(s) described for each reaction. Specify all
aspects of the stereochemistry.
a. stereospecific anti addition of bromine to cis- and trans-cinnamic acid.
b. methanolysis of S-3-bromooctane with 6% racemization.
c. stereospecific syn thermal elimination of acetic acid from 1R,2S-
diphenylpropyl acetate
d. stereoselective epoxidation of bicyclo[2.2.1]hept-2-ene proceeding 94% from
the exo face.

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