ne reducible representation for the molecular motion of tne molecule ICl5 (trigonal bipyramidal, point group D3hl, Is given in thne ble.D3H character table.pdf olecular Motion, ICI5.pdf. educe the representation and determine which are Raman and IR active. E 2C3 3C, 2S3 3ơ, A,' ² + y?, z? 1 1 1 1 1 A,' 1 -1 -1 R, E' 2 -1 -1 (x, y) (2 – y, xy) A," 1 1 1 -1 -1 -1 A," 1 -1 1 E" 1 (R,, R,) (xz, yz) 30p D3h T3N E 2C3 3C2 On 253 18 6

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter15: Introduction To Electronic Spectroscopy And Structure
Section: Chapter Questions
Problem 15.57E
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The reducible representation for the molecular motion of the molecule ICI5 (trigonal bipyramidal, point group D3h), is given in the attached
table.D3H character table.pdf
Molecular Motion, ICI5.pdf.
Reduce the representation and determine which are Raman and IR active.
E
2C3
3C2
2S3
30,
A,'
1
1
1
x² + y°, z?
1
1
1
A2'
1
1
-1
1
1
-1
R.
E'
2
-1
2
-1
(х, у)
(? – y, xy)
A,"
1
1
1
-1
-1
A,"
1
1
-1
-1
1
E"
2
-1
(R. R,)
(xz. yz)
D3h
E
2C3
3C2
On
253
T3N
18
Transcribed Image Text:The reducible representation for the molecular motion of the molecule ICI5 (trigonal bipyramidal, point group D3h), is given in the attached table.D3H character table.pdf Molecular Motion, ICI5.pdf. Reduce the representation and determine which are Raman and IR active. E 2C3 3C2 2S3 30, A,' 1 1 1 x² + y°, z? 1 1 1 A2' 1 1 -1 1 1 -1 R. E' 2 -1 2 -1 (х, у) (? – y, xy) A," 1 1 1 -1 -1 A," 1 1 -1 -1 1 E" 2 -1 (R. R,) (xz. yz) D3h E 2C3 3C2 On 253 T3N 18
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