The following character table (accompanied by a molecule of the corresponding point group) has some missing information. 2 C3 3 C2 2 S3 3 ov X1 1 1 1 1 1 1 x2+ y?, z2 1 1 -1 1 1 -1 Rz E' 2 -1 2 -1 (x, y) (x2- y?, xy) A;" 1 X2 1 -1 -1 -1 Az" 1 1 -1 -1 -1 1 X3 BH; E" -1 -2 1 (Rx, Ry) (2х, yz) а. Based on symmetry labels and Mulliken symbols, what is the missing symmetry element? b. Provide the missing information in the table: i. X1 = ii. X2 = iii. X3 = С. For this point group, what is the symmetry of the following orbitals for an atom located along the main C3 axis? i. A px orbital: ii. A d? orbital: iii. A dxy orbital:

The following character table (accompanied by a molecule of the corresponding point group) has some missing information. 2 C3 3 C2 2 S3 3 ov X1 1 1 1 1 1 1 x2+ y?, z2 1 1 -1 1 1 -1 Rz E' 2 -1 2 -1 (x, y) (x2- y?, xy) A;" 1 X2 1 -1 -1 -1 Az" 1 1 -1 -1 -1 1 X3 BH; E" -1 -2 1 (Rx, Ry) (2х, yz) а. Based on symmetry labels and Mulliken symbols, what is the missing symmetry element? b. Provide the missing information in the table: i. X1 = ii. X2 = iii. X3 = С. For this point group, what is the symmetry of the following orbitals for an atom located along the main C3 axis? i. A px orbital: ii. A d? orbital: iii. A dxy orbital:

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter13: Introduction To Symmetry In Quantum Mechanics

Section: Chapter Questions

Problem 13.26E: Determine the point groups of the following molecules. a Hydrogen peroxide, H2O2 it is not planar. b...

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