Number of Number of Mp ("C) C atoms C=C bonds Structure Name Saturated fatty acids 12 CH3(CHH0CO;H lauric acid 44 14 CH(CH)12CO,H myristic acid 58 16 CHнCHh.CO,H palmitic acid 63 18 CH3(CH)1,CO,H stearic acid 69 20 CH3(CH1BCO;H arachidic acid 77 Unsaturated fatty acids 16 CH3(CH);CH=CH(CH),CO,H palmitoleic acid 18 CH,(CH,),CH=CH(CH,),CO,H oleic acid 18 CH(CH).(CH=CHCH»(CH),CO,H linoleic acid -5 18 CH;CH2(CH= CHCH(CH,),CO,H linolenic acid -11 20 4 CH,(CH,),(CH=CHCH,),(CH,),CO,H arachidonic acid -49

Organic Chemistry
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Chapter26: Biomolecules: Amino Acids, Peptides, And Proteins
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How would you expect the melting point of eicosapentaenoic acid [CH3CH2(CH = CHCH2)5(CH2)2COOH] to compare with the melting points of the fatty acids listed in Table 31.2?

Table 31.2: The Most Common Fatty Acids in Triacylglycerols

Number of
Number of
Mp
("C)
C atoms
C=C bonds
Structure
Name
Saturated fatty acids
12
CH3(CHH0CO;H
lauric acid
44
14
CH(CH)12CO,H
myristic acid
58
16
CHнCHh.CO,H
palmitic acid
63
18
CH3(CH)1,CO,H
stearic acid
69
20
CH3(CH1BCO;H
arachidic acid
77
Unsaturated fatty acids
16
CH3(CH);CH=CH(CH),CO,H
palmitoleic acid
18
CH,(CH,),CH=CH(CH,),CO,H
oleic acid
18
CH(CH).(CH=CHCH»(CH),CO,H
linoleic acid
-5
18
CH;CH2(CH= CHCH(CH,),CO,H
linolenic acid
-11
20
4
CH,(CH,),(CH=CHCH,),(CH,),CO,H
arachidonic acid
-49
Transcribed Image Text:Number of Number of Mp ("C) C atoms C=C bonds Structure Name Saturated fatty acids 12 CH3(CHH0CO;H lauric acid 44 14 CH(CH)12CO,H myristic acid 58 16 CHнCHh.CO,H palmitic acid 63 18 CH3(CH)1,CO,H stearic acid 69 20 CH3(CH1BCO;H arachidic acid 77 Unsaturated fatty acids 16 CH3(CH);CH=CH(CH),CO,H palmitoleic acid 18 CH,(CH,),CH=CH(CH,),CO,H oleic acid 18 CH(CH).(CH=CHCH»(CH),CO,H linoleic acid -5 18 CH;CH2(CH= CHCH(CH,),CO,H linolenic acid -11 20 4 CH,(CH,),(CH=CHCH,),(CH,),CO,H arachidonic acid -49
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