O Chemical ReactionsDilution3/5[A chemist must prepare 125. mL of 180. mM aqueous copper(II) sulfate (CuSO4) working solution. He'll do this by pouring out some 0.198molaqueousLcopper(II) sulfate stock solution into a graduated cylinder and diluting it with distilled water.Calculate the volume in mL of the copper(II) sulfate stock solution that the chemist should pour out. Round your answer to 3 significant digits.Oml.G

Step 1: Convert the molarity of the needed solution to moles/L (M).Step 2: The required volume of…

Answered: O Chemical Reactions Dilution 3/5 [ A…

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter15: Acid–base Equilibria

Section: Chapter Questions

Problem 98AP

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On Easter Sunday, April 3, 1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: 2HNO3(aq)+Na2CO3(aq)2NaNO3(aq)+H2O(l)+CO2(g) a. Calculate H for this reaction. Approximately 2.0 104 gal nitric acid was spilled. Assume that the acid was an aqueous solution containing 70.0% HNO3 by mass with a density of 1.42 glcm3. What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? (Hf for NaNO3(aq) = 467 kJ/mol) b. According to The Denver Post for April 4, 1983, authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of H, what was their major concern?
94. Baking soda (sodium hydrogen carbonate. NaHCO3) is often used to neutralize spills of acids on the benchtop in the laboratory. What mass of NaHCO3 would be needed to neutralize a spill consisting of 25.2 mL of 6.01 M hydrochloric acid solution?
You wish to prepare 1 L of a 0.02-M potassium iodate solution. You require that the final concentration be within 1% of 0.02 M and that the concentration must be known accurately to the fourth decimal place. How would you prepare this solution? Specify the glassware you would use, the accuracy needed for the balance, and the ranges of acceptable masses of KIO3 that can be used.
What mass of solid NaOH (97.0% NaOH by mass) is required to prepare 1.00 L of a 10.0% solution of NaOH by mass? The density of the 10.0% solution is 1.109 g/mL.
What mass of HCl is contained in 45.0 mL of an aqueous HCl solution that has a density of 1.19 g cm-3 and contains 37.21% HCl by mass?
Many over-the-counter antacid tablets are now formulated using calcium carbonate as die active ingredient, which enables such tablets to also be used as dietary calcium supplements. As an antacid for gastric hyperacidity, calcium carbonate reacts by combining with hydrochloric acid found in the stomach, producing a solution of calcium chloride, converting die stomach acid to water, and releasing carbon dioxide gas (which the person suffering from stomach problems may feel as a burp). Write die balanced chemical equation for this process.
You are given a 1.50-g mixture of sodium nitrate and sodium chloride. You dissolve this mixture into 100 mL of water and then add an excess of 0.500 M silver nitrate solution. You produce a white solid, which you then collect, dry, and measure. The white solid has a mass of 0.641 g. a. If you had an extremely magnified view of the solution (to the atomic-molecular level), list the species you would see (include charges, if any). b. Write the balanced net ionic equation for the reaction that produces the solid. Include phases and charges. c. Calculate the percent sodium chloride in the original unknown mixture.
The units of parts per million (ppm) and parts per billion (ppb) are commonly used by environmental chemists. In general, 1 ppm means 1 part of solute for every 106 parts of solution. Mathematically, by mass: ppm=gsolutegsolution=mgsolutekgsolution In the case of very dilute aqueous solutions, a concentration of 1.0 ppm is equal to 1.0 g of solute per 1.0 mL, which equals 1.0 g solution. Parts per billion is defined in a similar fashion. Calculate the molarity of each of the following aqueous solutions. a. 5.0 ppb Hg in H2O b. 1.0 ppb CHCl3 in H2O c. 10.0 ppm As in H2O d. 0.10 ppm DDT (C14H9Cl5) in H2O
A student wants to prepare 1.00 L of a 1.00-M solution of NaOH (molar mass = 40.00 g/mol). If solid NaOH is available, how would the student prepare this solution? If 2.00 M NaOH is available, how would the student prepare the solution? To help ensure three significant figures in the NaOH molarity, to how many significant figures should the volumes and mass be determined?
Many over-the-counter antacid tablets are now formulated using calcium carbonate as the active ingredient, which enables such tablets to also be used as dietary calcium supplements. As an antacid for gastric hyperacidity, calcium carbonate reacts by combining with hydrochloric acid found in the stomach, producing a solution of calcium chloride, converting the stomach acid to water, and releasing carbon dioxide gas (which the person suffering from stomach problems may feel as a “burp”). Write the unbalanced chemical equation for this process.
In the spectroscopic analysis of many substances, a series of standard solutions of known concentration are measured to generate a calibration curve. How would you prepare standard solutions containing 10.0, 25.0, 50.0, 75.0, and 100. ppm of copper from a commercially produced 1000.0-ppm solution? Assume each solution has a final volume of 100.0 mL. (See Exercise 123 for definitions.)

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