One of the more striking hydride complexes is [ReH9]2-, which has tricapped trigonal prismatic geometry. Construct a representation using the hydrogen orbitals as a basis. Reduce this to its component irreducible representations, and indicate which orbitals of Re are of suitable symmetry to interact with the hydrogen orbitals.

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A: Here, we need to explain the formation of complex B by using ligand A by employing concept of Hard…

Q: Ligand A, B, and C form complexes with a metal cation resulting to  violet, indigo, and blue aqueous…

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Q: Which ligand below gives the LEAST stability to Pd2+ in forming a square planar complex? О а. NH3 O…

A: a) NH3 will form the least stable complex.  Because we know that more is the basicity of lignad more…

Q: Hexaamminechromium(III) ion, [Cr(NH3)6]°* is a metal complex containing six ammonia ligands i. Using…

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Q: The metal ion, M2+, formed a paramagnetic tetrahedral complex [MJ4]2+, having three unpaired…

A: Given: We have to calculate the hybridization of given M2+ ion.

Q: the complex [CrO7]² is bright orange colored, suggest reason for that ?

A: In this question, we will discuss about why complex [Cr2O7]2- ion is bright orange color.  You can…

Q: Draw a molecular orbital diagram to show that CH3 molecule is a ơ-donor ligand.

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Q: Molecular nitrogen (N2) can act as a ligand in certaincoordination complexes. Predict the structure…

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Q: The octahedral ion complex [CoF6] 3‒ absorbs at 675 nm. (a) What color is the complex? (b)…

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Q: In the octahedral field, dx2-v2 and d,2 are denoted as e, orbitals with the s-symmetry while dxy,…

A: In octahedral field, the molecular orbital diagram in different kind of ligand is different.…

Q: Draw one facial and one meridional (fac- and mer-) isomer of the coordination complex of the general…

A: In  MX3 Y3 octahedral compound , if three identical ligand occupy one face of octahedron,  it is…

Q: Ligands X, Y, and Z form octahedral complexes with Cu2* ion resulting to yellow, orange, and red…

A: ✓Following is the increasing order of ligand field strength Z<Y<X So the correct answer is (C)…

Q: Show how the coordination of two MeHNCH2CH2NH2 ligands to a metal atom in a square planar complex…

A: Optical isomers: Two compound having same molecular formula but different in spatial arrangement…

Q: Hexaamminechromium(III) ion, [Cr(NH3)s]³* is a metal complex containing six ammonia ligands i. Using…

A: A question based on coordination compounds that is to be accomplished.

Q: 3. The coordination geometries around the nickel atom in the nominally six-coordinate complexes…

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Q: 2) draw the MO diagrams to show the effect of pi-back bonding in the square planar metal complexes…

A: THE SOLUTION IS SHOWN BELOW.

Q: 4. The structure of [Cu(NH3)4]²+ is known to be square planar. Using the ligand o orbitals only,…

A: Given that  Square planer metal complex [Cu(NH3)4]2+ (ML4) Draw orbitals symmetries of the central…

Q: Take the following complexes into account: A)[Co(en);]I3 B) Liq[COF3(OH)3] a) Which type of…

A: Hello. Since your question has multiple sub-parts, we will solve the first three sub-parts for you.…

Q: Define the ambidentate ligand and give two examples.

A: Those ligand which can donate electrons from two different atom site but donate from 1 site at one…

Q: A complex of metal M"+ has the following electronic distribution ind orbitals, 1l E The neutral M…

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Q: Draw a molecular orbital diagram to show that CH3¯ molecule is a -donor ligand.

A: A molecular orbital diagram, or MO diagram, is a qualitative descriptive tool explaining chemical…

Q: An octahedral complex, MA,B2C2 (A, B, C are all monodentate ligands), has a total of 6…

A: The correct option is as follows:

Q: 1. Draw the partial MO diagram for a [Fe(OH;)6J** using concepts from Ligand Field Theory. Fill in…

A: Hello. Since your question has multiple parts, we will solve the first question for you. If you want…

Q: The metal ion, M2+, formed a paramagnetic tetrahedral complex [MJ4]2+, having three unpaired…

A: The given metal ion is M2+

Q: Draw molecular orbital diagram, write complete electronic configuration and calculate bond order for…

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Q: Mo(PMes)3(C6HS)2

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Q: Two transition metal complexes, FA, & GB, (where A & B represent the ligands; and F and G the…

A: Here I have calculated wavelength from the frequency data , which is quite easy. Next I have matched…

Q: Find SALCs and construct the MO diagram for a transition metal complex with octahedral symmetry.

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Q: The factor determining the mechanism observed in the substitution reactions of square plane…

A: here, for the nucleophilic substitution reaction Sn2 for the inorganic reaction mechanism  yes, This…

Q: Cis-diamminedichloroplatinum (II) or “cisplatin” is a square planar complex with the formula…

A: The structure of cis-platin and trans-platin is shown as follows: Among Geometrical Isomers,…

Q: The two egorbitals are identical in energy in an octahedralcomplex but have different energies in a…

A: The ligands are electron donors and they can donate the unshared electron pairs to the electrophilic…

Q: Many coordination complexes are used in medicines. Well known coordination complexe used in medical…

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Q: Consider the following metal ion d-electron configuration and crystal field in octahedral complexes:…

A: If all the six ligands approaching the metal cation surround it spherically symmetric i.e. all the…

Q: What are the characters for the operations C2, C4, σd, and σv(xz) respectively, on the LCAO Ψ(L1+L3)…

A: Cn is a rotation of (360/n)". C2= 180°rotation, C4= 90°rotation

Q: cl CI N=

A: The group of symmetry components found in a molecule is referred to as a point group.

Q: Determine the symmetry of the orbital groups for the donor sigma bonds (σ) of the ligand in an…

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Q: A shortcut to finding optical isomers is to see if the complexhas a plane of symmetry—a plane…

A: Optically active compounds should not have a plane of symmetry in them. These molecules has the…

Q: What electronic feature must a donor atom of a ligand have?

A: A donor is an atom or group of atoms whose highest filled atomic orbital or molecular orbital is…

Q: Are bipyridines (bipy) and analogous amines, phenanthroline (phen) and terpyridine (terpy) chelate…

A: Yes, bipyridine and analogous amines, phenanthroline and terpyridine are chelate ligands.

Q: According to the theory of molecular orbitals, how are ligands classified and what effect do they…

A: On the basis of molecular orbital Theory , ligands are classified into :  1.) Only sigma donor 2.)…

Q: For each of the following complexe ate) and give its magnetic propertie 3. [Fe(NH,),J²* [Cr(CO),J*

A: Concept is based on spectrochemical series. It decides the spin of ligands.

Q: Which is correct and which is incorrect from the following sentences? In any case, give a brief…

A: Here we have to predict the true or false statement from the following given statements.

Q: A complex of the type [M(AA)2X2]n+ is optically active,giving a suitable example. comment on the…

A: If the substances  which is under observation are non-superimposable mirror images of each other and…

Q: What are the characteristics of outer orbital complexes for octahedral complexes 1_hybridization is…

A: When the inner d orbital is used for hybridization then it is inner orbital complex . But when it is…