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- (II) A 1.0-L volume of air initially at 3.5 atm of (gauge)pressure is allowed to expand isothermally until the pressureis 1.0 atm. It is then compressed at constant pressure to itsinitial volume, and lastly is brought back to its originalpressure by heating at constant volume. Draw the processon a PV diagram, including numbers and labels for the axesOne hundred mole NH3/s and 200 mole O2/s at 25 degrees C are fed into a reactor in which the ammonia is completely consumed. The product gas emerges at 300 degreesC. Calculate the rate at which heat must be transferred to or from thereactor, assuming operation at approximately 1 atm. The standard heat ofreaction for the oxidation of ammonia is given below: NH3 (g) + 5O2 (g) → 4NO(g) + 6H2O(v); ΔHr^0= -904.7KJ(ΔHr^0-904.76KJ/s)ΔfusionH of H2O at 0oC is 6008.2 J mol-1. The values of the heat capacity, Cp,m for the solid and liquid forms are 37.24 and 75.31 J K-1 mol-1, respectively. Calculate (a) ΔH, (b) ΔS and (c) ΔG for the process H2O(s, -10oC) → H2O(l, -10oC) at a constant pressure of 1 atm. Answer: 5627; 20.5; 235.5
- A sample containing 2.05 moles of an ideal gas with CV = 20.1 J K-1 is initially at 3.84 bar and 300. K. It is compressed at constant volume until its pressure reaches 5.62 bar. Calculate the final temperature, work done, heat transferred, ΔU, ΔH and ΔS for the process.3 Calculate ∆G for the process during which 10 mmol He(g) which initially occupies a volume of 500 cm3, expands isothermally to a final volume of 5 dm3 at 298.15 K.A piston/cylinder arrangement contains one mole of an ideal gas (the system) initially at 10.0 atm pressure and 300 K, as shown in the accompanying illustration. Neglecting the mass of the piston, neglecting friction, and assuming isothermal conditions throughout, the pin restraining the piston is removed. For the resulting process: (g = 9.807 m sR7) (a) What is qsyst if the mass of the weight is zero? (b) What is qsyst if the mass of the weight is 100 kg? (c) What is qsyst if the mass of the weight is 1017.4 kg?
- A rigid insulated tank is divided into 2 equal compartments by athin rigid partition. One of the compartments contains air, assumedto be an ideal gas at 800 kPa and 250◦C. The other compartment isunder a vacuum. The partition is suddenly broken and the air rushesinto the evacuated compartment. The tank pressure and temperatureeventually equilibrate. (a) what is the final temperature of the gas ◦C?(b) what is the final pressure, kPa?(c) how much work is done by the system, kJ/kg?(d) how much heat is transferred to the system kJ/kg●The standard heat of reaction for the oxidation of ammonia is given below: 4 NH3 (g) + 5 O2 (g) 4 NO (g) + 6 H2O (v) ΔĤ°r=-904.7 kJ/mol 100 mol NH3/s and 200 mol O2/s at 25C are fed into a reactor in which the ammonia is completely consumed. The products gas emerges at 300C. Calculate the rate at which heat must be transferred to or from the reactor, assuming operation at approximately 1 atm.6. As shown in Figure, a gas within a piston-cylinder assembly undergoes a thermodynamic cycle consisting of three processes in series: Process 1-2: Compression with U 2 =U 1 . Process 2-3: Constant-volume cooling to p 3 =140 kPa,; V 3 =0.028 m^ 2 . Process 3 - 1 : Constant-pressure expansion with W 31 =10.5 kJ. For the cycle, W eycle =28.3 kJ . There are no changes in kinetic or potential energy. Determine (a) the volume at state 1, in m ^ 3 . (b) the work and heat transfer for process 1-2, each in kJ. (e) Can this be a power cycle? A refrigeration cycle? Explain.
- A student poured 100 ml of water (density = 1.00 g / mL) into a coffee calorimeter, noted that the temperature of the water was 18.8oC, then added 5.33 g KOH. With the lid on, the mixture was stirred, temperature increased and the maximum temperature reached at the time of mixing 31.6 oC. Calculate the heat of the system in this dissolution reaction (qsys). ( Approximate the specific heat capacity, cp as 4.18 J g-1 K-1. Do not consider the contribution to the heat generated from the calorimeter; assume that this is zero. Only calculate the heat from the heat capacity of the solution. make sure you consider the sign of qsys qsys for dissolution of KOH = J19. Solid urea, (NH2)2CO, burns to give CO2, N2, and liquid H2O. Its heat of combustion is -632.2 kJ/mol. 1.Write the balanced combustion equation. Record fractions as ratios (e.g. 1/2) if needed. Include aggregation states in your answer. 2.Calculate the heat generated per mole of H2O formed to 0.1 kJ. 3.Using this heat of combustion and the appropriate thermodynamic data, determine the heat of formation of urea to 0.1 kJ.A chemical reaction takes place inside a flask submerged in a water bath. The water bath contains 4.70 kg of water at 37.5C. During the reaction 92.8kJ of heat flows out of the flask and into the bath. Calculate the new temperature of the water bath. Heat capacity of water is 4.18J.g-1.K-1. Round your answer to 3