Ozone in the lower atmosphere is a pollutant that can form by the following reaction involving the oxidation of unburned hydrocarbons: ​​CH4 (g)   +   8 O2 (g)    à     CO2 (g)    +   2 H2O (g)  +  4 O3 (g)    ​​ΔG° = ?​ ​The standard enthalpy change is 51.24 kJ and the following values are known for ΔS°.   a. Calculate ΔS° for this reaction: b.  Determine ΔG° based on the given ΔH° and ΔS° calculated in part 1a at 25°C: c.  Is this reaction spontaneous?  Calculate at what temperature the reaction would change from spontaneous to non-spontaneous or vice versa.

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Chapter10: Entropy And The Second Law Of Thermodynamics
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Ozone in the lower atmosphere is a pollutant that can form by the following reaction involving the oxidation of unburned hydrocarbons:

​​CH4 (g)   +   8 O2 (g)    à     CO2 (g)    +   2 H2O (g)  +  4 O3 (g)    ​​ΔG° = ?​

​The standard enthalpy change is 51.24 kJ and the following values are known for ΔS°.

 

a. Calculate ΔS° for this reaction:

b.  Determine ΔG° based on the given ΔH° and ΔS° calculated in part 1a at 25°C:

c.  Is this reaction spontaneous?  Calculate at what temperature the reaction would change from spontaneous to non-spontaneous or vice versa.

 

 

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