(p) Trace the hemiacetal in the following monosaccharide: CH₂OH O CH₂OH OH OH OH (q) Identify the anomeric carbon in the following monosaccharide: CH OH O H OH OH CH₂OH OH (r) Classify the above monosaccharide as a beta sugar or an alpha sugar. H Н (s) Identify and classify the glycosidic bond in the following disaccharide: ОН ОН CH₂OH OH CH₂OH ОН OH ОН

Organic And Biological Chemistry
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Author:STOKER, H. Stephen (howard Stephen)
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Chapter9: Proteins
Section: Chapter Questions
Problem 9.58EP
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(0) Draw structural formula for the product that is formed when structure II is treated with
the reagents shown below.
11
(p) Trace the hemiacetal in the following monosaccharide:
CH₂OH O.
CH₂OH
OH
OH
H
OH
OH
(q) Identify the anomeric carbon in the following monosaccharide:
CH₂OH O
H
1. Br₂, H₂O
2. Ca(OH)₂
3. H₂O₂/Fe³*
OH
CH₂OH
H
OH
O
H
(r) Classify the above monosaccharide as a beta sugar or an alpha sugar.
OH OH
H
(s) Identify and classify the glycosidic bond in the following disaccharide:
CH₂OH
CH₂OH
OH/
H
H
OH
O
OH OH
Transcribed Image Text:(0) Draw structural formula for the product that is formed when structure II is treated with the reagents shown below. 11 (p) Trace the hemiacetal in the following monosaccharide: CH₂OH O. CH₂OH OH OH H OH OH (q) Identify the anomeric carbon in the following monosaccharide: CH₂OH O H 1. Br₂, H₂O 2. Ca(OH)₂ 3. H₂O₂/Fe³* OH CH₂OH H OH O H (r) Classify the above monosaccharide as a beta sugar or an alpha sugar. OH OH H (s) Identify and classify the glycosidic bond in the following disaccharide: CH₂OH CH₂OH OH/ H H OH O OH OH
3. Draw the form of the amino acid that predominates at pH 11. (
H₂N-CH-
pKa = 9.60
CH₂
pKa = 8.95
c=0
OH
pKa = 3.65
4. At what pH will the following amino acid no longer migrate in an electric field?
H₂N-CH-
(CH2)4
pKa = 8.95
NH₂
pKa = 10.53
H₂N-CH-
C
5. Draw the form of the amino acid that predominates at pH 6.
(CH2)4
O
OH
pKa = 1.88
C
NH₂
pKa = 10.53
-OH
pKa = 2. 18
-OH
pKa = 2.18
6. All the following forces help to stabilize the tertiary and quaternary structures except:
(a) Hydrophobic interactions of nonpolar side chains
(b) Hydrogen bonding
(c) Electrostatic interactions between ionic groups
(d) Disulfide bonds
(e) Metallic bonds
Transcribed Image Text:3. Draw the form of the amino acid that predominates at pH 11. ( H₂N-CH- pKa = 9.60 CH₂ pKa = 8.95 c=0 OH pKa = 3.65 4. At what pH will the following amino acid no longer migrate in an electric field? H₂N-CH- (CH2)4 pKa = 8.95 NH₂ pKa = 10.53 H₂N-CH- C 5. Draw the form of the amino acid that predominates at pH 6. (CH2)4 O OH pKa = 1.88 C NH₂ pKa = 10.53 -OH pKa = 2. 18 -OH pKa = 2.18 6. All the following forces help to stabilize the tertiary and quaternary structures except: (a) Hydrophobic interactions of nonpolar side chains (b) Hydrogen bonding (c) Electrostatic interactions between ionic groups (d) Disulfide bonds (e) Metallic bonds
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