P2D.2 Starting from the expression Cp − CV = T(∂p/∂T)V(∂V/∂T)p, use the appropriate relations between partial derivatives (The chemist’s toolkit 9 in Topic 2A) to show that C C T V T V p ( / ) ( / ) p V p T

P2D.2 Starting from the expression Cp − CV = T(∂p/∂T)V(∂V/∂T)p, use the appropriate relations between partial derivatives (The chemist’s toolkit 9 in Topic 2A) to show that C C T V T V p ( / ) ( / ) p V p T

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

P2D.2 Starting from the expression Cp − CV = T(∂p/∂T)V(∂V/∂T)p, use the
appropriate relations between partial derivatives (The chemist’s toolkit 9 in
Topic 2A) to show that
C C
T V T
V p
( / )
( / ) p V
p
T

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P2D.2 Starting from the expression Cp − CV = T(∂p/∂T)V(∂V/∂T)p, use theappropriate relations between partial derivatives (The chemist’s toolkit 9 inTopic 2A) to show thatC CT V TV p( / )( / ) p VpT2− = ∂ ∂∂ ∂ Use this expression to evaluate Cp − CV for a perfect gas.