Part AAs a technician in a large pharmaceutical research firm, you need to produce 250. mL of a potassium dihydrogenphosphate buffer solution of pH = 6.93. The pK, of H2PO, is 7.21. You have the following supplies: 2.00 L of 1.00M KH2PO, stock solutign, 1.50 L of 1.00 M K2HPO, stock solution, and a carboy of pure distilled H2O.How much 1.00 M KH,PO, will you need to make this solution? (Assume additive volumes.)Express your answer to three significant digits with the appropriate units.> View Available Hint(s)

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Part A As a technician in a large pharmaceutical research firm, you need to produce 250. mL of a potassium dihydrogen phosphate buffer solution of pH = 6.93. The pK, of H;PO, is 7.21. You have the following supplies: 2.00 L of 1.00 M KH;PO, stock solutign, 1.50 L of 1.0o M K2HPO, stock solution, and a carboy of pure distilled H,O. How much 1.00 M KH,PO, will you need to make this solution? (Assume additive volumes.) Express your answer to three significant digits with the appropriate units. > View Available Hint(s)

Part A As a technician in a large pharmaceutical research firm, you need to produce 250. mL of a potassium dihydrogen phosphate buffer solution of pH = 6.93. The pK, of H;PO, is 7.21. You have the following supplies: 2.00 L of 1.00 M KH;PO, stock solutign, 1.50 L of 1.0o M K2HPO, stock solution, and a carboy of pure distilled H,O. How much 1.00 M KH,PO, will you need to make this solution? (Assume additive volumes.) Express your answer to three significant digits with the appropriate units. > View Available Hint(s)

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter14: Equilibria In Acid-base Solutions

Section: Chapter Questions

Problem 51QAP: Consider a 10.0% (by mass) solution of hypochlorous acid. Assume the density of the solution to be...

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When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence point is reached when 35.00 mL base has been added. After 20.00 mL NaOH solution has been added, the titration mixture has a pH of 5.75. Calculate the ionization constant of the acid.
Ammonia gas is bubbled into 275 mL of water to make an aqueous solution of ammonia. To prepare a buffer with a pH of 9.56, 15.0 g of NH4Cl are added. How many liters of NH3; at 25C and 0.981 atm should be used to prepare the buffer? Assume no volume changes and ignore the vapor pressure of water.
A good buffer generally contains relatively equal concentrations of weak acid and conjugate base. If you wanted to buffer a solution at pH = 4.00 or pH = 10.00, how would you decide which weak acidconjugate base or weak baseconjugate acid pair to use? The second characteristic of a good buffer is good buffering capacity. What is the capacity of a buffer? How do the following buffers differ in capacity? How do they differ in pH? 0.01 M acetic acid/0.01 M sodium acetate 0.1 M acetic acid/0.1 M sodium acetate 1.0 M acetic acid/1.0 M sodium acetate
A diprotic acid, H2B(MM=126g/moL), is determined to be a hydrate, H2B xH2O. A 10.00-g sample of this hydrate is dissolved in enough water to make 150.0 mL of solution. Twenty-five milliliters of this solution requires 48.5 mL of 0.425 M NaOH to reach the equivalence point. What is x?
Malonic acid (HO2CCH2CO2H) is a diprotic acid. In the titration of malonic acid w ith NaOH, stoichiometric points occur at pH = 3.9 and 8.8. A 25.00-mL sample of malonic acid of unknown concentration is titrated with 0.0984 M NaOH, requiring 31.50 mL of the NaOH solution to reach the phenolphthalein end point. Calculate the concentration of the initial malonic acid solution. (Sec Exercise 113.)
What mass of NH4Cl must be added to 0.750 L of a 0.100-M solution of NH3 to give a buffer solution with a pH of 9.26? (Him: Assume a negligible change in volume as the solid is added.)
Consider a 10.0% (by mass) solution of hypochlorous acid. Assume the density of the solution to be 1.00 g/mL. A 30.0-mL sample of the solution is titrated with 0.419 M KOH. Calculate the pH of the solution (a) before titration. (b) halfway to the equivalence point. (c) at the equivalence point.
Each symbol in the box below represents a mole of a component in one liter of a buffer solution; represents the anion (X-), = the weak acid (HX), = H+, and =OH. Water molecules and the few H+ and OH- ions from the dissociation of HX and X- are not shown. The box contains 10 mol of a weak acid, , in a liter of solution. Show what happens upon (a) the addition of 2 mol of OH- (2 ). (b) the addition of 5 mol of OH- (5 ). (c) the addition of 10 mol of OH- (10 ). (d) the addition of 12 mol of OH- (12 ). Which addition (a)-(d) represents neutralization halfway to the equivalence point?
K4 for acetic acid is 1.7 105 at 25C. A buffer solution is made by mixing 52.1 mL of 0.122 M acetic acid with 46.1 mL of 0.182 M sodium acetate. Calculate the pH of this solution at 25C after the addition of 5.82 mL of 0.125 M NaOH.
A solution consisting of 25.00 g NH4Cl in 178 mL of water is titrated with 0.114 M KOH. (a) How many milliliters of KOH are required to reach the equivalence point? (b) Calculate [Cl-], [K+], [NH3], and [OH-] at the equivalence point. (Assume that volumes are additive.) (c) What is the pH at the equivalence point?