Perchlorate is a serious problem in drinking water as it interfere with the functioning of thyroid hormone. It is monitored using ISE.A perchlorate ISE and SCE reference electrode are immersed in a solution containing 1.0x10-4 M solution of NaCl04. The cell potential is -0.146 V. The electrodes are transferred to a drinking water sample and the cell potential is -0.206 V. Calculate the concentration of perchlorate in the sample. Answer the following questions: i). The value of the constant in voltage is ii) Using the constant from i) above, write the expresion for the determination of the concentration of CIO4-in the drinking water sample iii) The concentration of CIO4 in the drinking water sample in mmole/L
Perchlorate is a serious problem in drinking water as it interfere with the functioning of thyroid hormone. It is monitored using ISE.A perchlorate ISE and SCE reference electrode are immersed in a solution containing 1.0x10-4 M solution of NaCl04. The cell potential is -0.146 V. The electrodes are transferred to a drinking water sample and the cell potential is -0.206 V. Calculate the concentration of perchlorate in the sample. Answer the following questions: i). The value of the constant in voltage is ii) Using the constant from i) above, write the expresion for the determination of the concentration of CIO4-in the drinking water sample iii) The concentration of CIO4 in the drinking water sample in mmole/L
Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter24: Coulometry
Section: Chapter Questions
Problem 24.4QAP: Halide ions can he deposited at a silver anode, the reaction being Ag(s) + X- AgX(s) +e- Suppose...
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