Consider the following reactions. Are they spontaneous in the direction written, under standard conditions at 25°C? Standard electrode potentials in aqueous solution at 25°C ar Standard Electrode (Reduction) Potentials in Aqueous Solution at 25°C Standard Cathode (Reduction) Half-Reaction Potential, E (V) Cu+ (aq) +e Cu* (aq) 0.16 Fe+ (aq) + e Fe?+ (aq) 0.77 O2 (9) + 4H (ag) + 4e 2H20(1) MnO, (ag) + 8H (aq) + 5e - Mn2+ (ag) + 4H2O(1) 1.49 1.23 a. Cu?+ (ag) + Fe2+ (ag) → Cu* (aq) + Fe+ (ag) spontaneous O nonspontaneous b. 4MNO, (ag) + 12H+ (ag) → 4MN²+ (aq) + 502 (9) + 6H2O(1) O spontaneous Ononspontaneous

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
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Chapter17: Electrochemistry
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Consider the following reactions. Are they spontaneous in the direction written, under standard conditions at 25°C? Standard electrode potentials in aqueous solution at 25°C are:
Standard Electrode (Reduction) Potentials in Aqueous Solution at 25°C
Cathode (Reduction)
Standard
Half-Reaction
Potential, E (V)
Cu²+ (ag) +e Cu* (aq)
0.16
Fe+ (ag) + e Fe2+ (ag)
0.77
O2 (9) + 4H (ag) + 4e - 2H20(1)
1.23
MnO4 (ag) + 8H* (aq) + 5e = Mn?+ (ag) + 4H2 0(1) 1.49
a. Cu?+ (ag) + Fe?+ (ag) → Cu* (aq) + Fe+ (ag)
O spontaneous
O nonspontaneous
b. 4MNO4 (ag) + 12H* (ag) → 4Mn?+ (ag) + 502(9) + 6H2O(1)
O spontaneous
Ononspontaneous
Transcribed Image Text:Consider the following reactions. Are they spontaneous in the direction written, under standard conditions at 25°C? Standard electrode potentials in aqueous solution at 25°C are: Standard Electrode (Reduction) Potentials in Aqueous Solution at 25°C Cathode (Reduction) Standard Half-Reaction Potential, E (V) Cu²+ (ag) +e Cu* (aq) 0.16 Fe+ (ag) + e Fe2+ (ag) 0.77 O2 (9) + 4H (ag) + 4e - 2H20(1) 1.23 MnO4 (ag) + 8H* (aq) + 5e = Mn?+ (ag) + 4H2 0(1) 1.49 a. Cu?+ (ag) + Fe?+ (ag) → Cu* (aq) + Fe+ (ag) O spontaneous O nonspontaneous b. 4MNO4 (ag) + 12H* (ag) → 4Mn?+ (ag) + 502(9) + 6H2O(1) O spontaneous Ononspontaneous
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