Consider the following reactions. Are they spontaneous in the direction written, under standard conditions at 25°C? Standard electrode potentials in aqueous solution at 25°C ar Standard Electrode (Reduction) Potentials in Aqueous Solution at 25°C Standard Cathode (Reduction) Half-Reaction Potential, E (V) Cu+ (aq) +e Cu* (aq) 0.16 Fe+ (aq) + e Fe?+ (aq) 0.77 O2 (9) + 4H (ag) + 4e 2H20(1) MnO, (ag) + 8H (aq) + 5e - Mn2+ (ag) + 4H2O(1) 1.49 1.23 a. Cu?+ (ag) + Fe2+ (ag) → Cu* (aq) + Fe+ (ag) spontaneous O nonspontaneous b. 4MNO, (ag) + 12H+ (ag) → 4MN²+ (aq) + 502 (9) + 6H2O(1) O spontaneous Ononspontaneous
Consider the following reactions. Are they spontaneous in the direction written, under standard conditions at 25°C? Standard electrode potentials in aqueous solution at 25°C ar Standard Electrode (Reduction) Potentials in Aqueous Solution at 25°C Standard Cathode (Reduction) Half-Reaction Potential, E (V) Cu+ (aq) +e Cu* (aq) 0.16 Fe+ (aq) + e Fe?+ (aq) 0.77 O2 (9) + 4H (ag) + 4e 2H20(1) MnO, (ag) + 8H (aq) + 5e - Mn2+ (ag) + 4H2O(1) 1.49 1.23 a. Cu?+ (ag) + Fe2+ (ag) → Cu* (aq) + Fe+ (ag) spontaneous O nonspontaneous b. 4MNO, (ag) + 12H+ (ag) → 4MN²+ (aq) + 502 (9) + 6H2O(1) O spontaneous Ononspontaneous
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter17: Electrochemistry
Section: Chapter Questions
Problem 59P
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