Phase changes occur between different solid forms, as well as from solid to liquid, liquid to gas, and solid to gas. When white tin at 1.00 atm is cooled below 13.2°C, it spontaneously changes (over a period of weeks) to gray tin. The density of gray tin is less than the density of white tin ( 5.75 g cm^-3 vs 7.31 g cm^-3 ). Some white tin is compressed to a pressure of 2.00 atm. At this pressure, should the temperature be higher or lower than 13.2°C for the conversion to gray tin to occur? Explain your reasoning.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter10: Solids, Liquids, And Phase Transitions
Section: Chapter Questions
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Phase changes occur between different solid forms, as well as from solid to liquid, liquid to gas, and solid to gas. When white tin at 1.00 atm is cooled below 13.2°C, it spontaneously changes (over a period of weeks) to gray tin. The density of gray tin is less than the density of white tin ( 5.75 g cm^-3 vs 7.31 g cm^-3 ). Some white tin is compressed to a pressure of 2.00 atm. At this pressure, should the temperature be higher or lower than 13.2°C for the conversion to gray tin to occur? Explain your reasoning. 

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