Phosphoric acid is a triprotic acid with the pK, values pKa1 = 2.148, pK2 = 7.198, and pK3 = 12.375. You wish to prepare 1.000 L of a 0.0400 M phosphate buffer at pH 7.780. To do this, you choose to mix the two salt forms involved in the second ionization, NaH, PO, and Na,HPO,, in a 1.000 L volumetric flask and add water to the mark. What mass of each salt will you add to the mixture? g mass NaH, PO, %3D mass Na, HPO, D What other combination of phosphoric acid and its salts could be mixed to prepare this buffer? | H,PO, and Na, HPO, H, PO, and NaH, PO, H, PO, and Na, PO,
Electronic Effects
The effect of electrons that are located in the chemical bonds within the atoms of the molecule is termed an electronic effect. The electronic effect is also explained as the effect through which the reactivity of the compound in one portion is controlled by the electron repulsion or attraction producing in another portion of the molecule.
Drawing Resonance Forms
In organic chemistry, resonance may be a mental exercise that illustrates the delocalization of electrons inside molecules within the valence bond theory of octet bonding. It entails creating several Lewis structures that, when combined, reflect the molecule's entire electronic structure. One Lewis diagram cannot explain the bonding (lone pair, double bond, octet) elaborately. A hybrid describes a combination of possible resonance structures that represents the entire delocalization of electrons within the molecule.
Using Molecular Structure To Predict Equilibrium
Equilibrium does not always imply an equal presence of reactants and products. This signifies that the reaction reaches a point when reactant and product quantities remain constant as the rate of forward and backward reaction is the same. Molecular structures of various compounds can help in predicting equilibrium.
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