physical chemistry, please solve question 13

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section: Chapter Questions
Problem 115QRT
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physical chemistry, please solve question 13

Q11: What is the basic assumption in a steady state approximation?
a) Products are being formed slower than reactants are regenerated
b) The first step in a mechanism always determines the rate of the reaction
c) Pre-equilibrium take place before the rate determining step
d) Products are being formed faster than reactants are regenerated
e) The concentrations of all intermediates are constant with time
Q12: Species that are formed in one step of reaction mechanism and used up in another step are
called
a) Transition states
d) Catalysts
Q13: What type of mechanism the following steps represent?
H+ Br2 → HBr + Br
H+ HBr →→ H₂ + Br
a) Simultaneous
d) Opposing
b) Intermediates.
e) Rate determining step
a) Co(NH3)sBr2+ + Hg2+
b) S₂O3²- + I
c) Fe²+ + Co(C₂O4)3³-
d) Co(NH3)5Br2+ + OH¯
e) None of the above
b) Parallel
e) Competition
c) Inhibitors
Q14: For which of the following reactants increasing the ionic strength of the solution will
increase the rate constant?
c) Consecutive
Q15: Which of the following plots represents only base catalyzed reaction?
a) Plot A
b) Plot B
c) Plot C
d) Plot B and C
e) Plot A and C
Log k
B
pH
Transcribed Image Text:Q11: What is the basic assumption in a steady state approximation? a) Products are being formed slower than reactants are regenerated b) The first step in a mechanism always determines the rate of the reaction c) Pre-equilibrium take place before the rate determining step d) Products are being formed faster than reactants are regenerated e) The concentrations of all intermediates are constant with time Q12: Species that are formed in one step of reaction mechanism and used up in another step are called a) Transition states d) Catalysts Q13: What type of mechanism the following steps represent? H+ Br2 → HBr + Br H+ HBr →→ H₂ + Br a) Simultaneous d) Opposing b) Intermediates. e) Rate determining step a) Co(NH3)sBr2+ + Hg2+ b) S₂O3²- + I c) Fe²+ + Co(C₂O4)3³- d) Co(NH3)5Br2+ + OH¯ e) None of the above b) Parallel e) Competition c) Inhibitors Q14: For which of the following reactants increasing the ionic strength of the solution will increase the rate constant? c) Consecutive Q15: Which of the following plots represents only base catalyzed reaction? a) Plot A b) Plot B c) Plot C d) Plot B and C e) Plot A and C Log k B pH
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